Zhiyuan Zhang, Zhiming Zhang, Jianqiu Wang, Hongliang Ming, Haipeng Zhu, Tichun Dan, Ruoyu Wang, Beibei Gao, En-Hou Han
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引用次数: 0
Abstract
The effect of polyacrylic acid (PAA) on the corrosion behavior of Alloy 690 in simulated pressurized water reactor secondary water was investigated. The duplex oxide film structure, consisting of a Ni-rich outer layer and a Cr-rich inner layer, was maintained regardless of PAA presence. PAA inhibited the growth of outer Ni-rich particles while promoting Cr enrichment in the inner layer and inducing its amorphization, both enhancing oxidation resistance. However, excess PAA (≥ 500 ppb) suppressed protective oxide formation during initial oxidation, leading to oxygen penetration into the matrix. A PAA concentration of around 250 ppb is considered optimal for steam generators, as it provides the benefits of PAA without adverse effects on the alloy.
期刊介绍：
Journal of Materials Science & Technology strives to promote global collaboration in the field of materials science and technology. It primarily publishes original research papers, invited review articles, letters, research notes, and summaries of scientific achievements. The journal covers a wide range of materials science and technology topics, including metallic materials, inorganic nonmetallic materials, and composite materials.
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