{"title":"Operando Spectroscopic Investigation of the Re<sub>2</sub>O<sub>7</sub>.2H<sub>2</sub>O Adduct obtained by Controlled Hydration of Re<sub>2</sub>O<sub>7</sub>.","authors":"Xavier Sécordel, Shreya Nandi, Asma Tougerti, Sylvain Cristol, Jean-François Paul, Valérie Briois, Camille La Fontaine, Elise Berrier","doi":"10.1002/cphc.202400432","DOIUrl":null,"url":null,"abstract":"<p><p>We provide here a comprehensive investigation spectroscopic of the controlled hydration of Re<sub>2</sub>O<sub>7</sub> using Raman, Fourier-Transform Infrared (FTIR) and X-Rays Absorption (XAS) techniques in complement with ab initio modelling for confirming the spectral assignments. Hence, the Raman signature of Re<sub>2</sub>O<sub>7</sub>.2H<sub>2</sub>O was obtained, and the evolution kinetics was investigated to provide a detailed description of the hydration process.</p>","PeriodicalId":9819,"journal":{"name":"Chemphyschem","volume":" ","pages":"e202400432"},"PeriodicalIF":2.3000,"publicationDate":"2025-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11747579/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemphyschem","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/cphc.202400432","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/11/20 0:00:00","PubModel":"Epub","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
We provide here a comprehensive investigation spectroscopic of the controlled hydration of Re2O7 using Raman, Fourier-Transform Infrared (FTIR) and X-Rays Absorption (XAS) techniques in complement with ab initio modelling for confirming the spectral assignments. Hence, the Raman signature of Re2O7.2H2O was obtained, and the evolution kinetics was investigated to provide a detailed description of the hydration process.
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ChemPhysChem is one of the leading chemistry/physics interdisciplinary journals (ISI Impact Factor 2018: 3.077) for physical chemistry and chemical physics. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
ChemPhysChem is an international source for important primary and critical secondary information across the whole field of physical chemistry and chemical physics. It integrates this wide and flourishing field ranging from Solid State and Soft-Matter Research, Electro- and Photochemistry, Femtochemistry and Nanotechnology, Complex Systems, Single-Molecule Research, Clusters and Colloids, Catalysis and Surface Science, Biophysics and Physical Biochemistry, Atmospheric and Environmental Chemistry, and many more topics. ChemPhysChem is peer-reviewed.
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