An entrained flow biomass gasification technology with the fluidized bed concept for low-carbon fuel production

Keigo Matsumoto
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Abstract

For accomplishing the vision of building of a net-emission zero society, low-carbon fuels such as e-fuel, Sustainable Aviation Fuel (SAF), and chemical products generation, plays a significant role. Especially, among the low carbon fuels, SAF is the most crucial. Ammonia and electric aircraft are under way as alternatives to fossil-derived jet fuel (kerosene). However, none of these have yet found their way to commercialization. Among the SAF production technology, biomass gasification and Fischer-Tropsch (FT) synthesis technology are one of the lowest CO2 emission processes, according to Life Cycle Assessment (LCA) analysis. However, at present there are some issues about biomass grinding, tar, ash treatment, gas purification and wastewater. We, at Mitsubishi Heavy Industries (MHI) R&D laboratory have developed entrained bed gasification, adopting the fluidized bed concept in which biomass particles are recirculated in the gasifier without fluidizer. Principally desired outcomes of this development was to reduce the grinding power, simplify the structure by using atmospheric pressure process, and lower tar concentration while maintain suitable temperature to prevent ash from melting inside gasifier. Empirical and actual results showed that the developed gasifier can obtain high carbon conversion ratio and low tar as compared to the traditional gasification processes for low-carbon fuel production and produce reliably stable syngas for low-carbon fuel synthesis with single gasifier. Based on the pilot plant operation results, effectiveness of moderate (1223 – 1323 K) temperature gasification with this concept has been demonstrated too. As a conclusion, development needs and expectation of gasification technology for contributing to carbon neutral society are mentioned.
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采用流化床概念的内流式生物质气化技术,用于生产低碳燃料
要实现建设零净排放社会的愿景,电子燃料、可持续航空燃料(SAF)和化学产品发电等低碳燃料发挥着重要作用。尤其是在低碳燃料中,可持续航空燃料(SAF)最为关键。氨和电动飞机作为化石喷气燃料(煤油)的替代品正在进行中。然而,这些技术都尚未实现商业化。根据生命周期评估(LCA)分析,在 SAF 生产技术中,生物质气化和费托合成(FT)技术是二氧化碳排放量最低的工艺之一。然而,目前在生物质研磨、焦油、灰处理、气体净化和废水处理方面还存在一些问题。我们三菱重工(MHI)研发实验室开发了内流床气化技术,采用流化床概念,生物质颗粒在气化炉中循环流动,不需要流化器。这项研发的主要预期成果是降低研磨功率,通过使用常压工艺简化结构,降低焦油浓度,同时保持合适的温度以防止灰烬在气化炉内熔化。经验和实际结果表明,与生产低碳燃料的传统气化工艺相比,所开发的气化炉可获得高碳转化率和低焦油,并可生产稳定的合成气,用于单气化炉低碳燃料合成。根据中试装置的运行结果,采用这一概念进行中温(1223 - 1323 K)气化的有效性也已得到证实。最后,还提出了气化技术的发展需求和期望,以促进碳中和社会的发展。
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