The effect of drying-wetting alternation on corrosion resistance of rusted weathering steel

IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY International Journal of Electrochemical Science Pub Date : 2024-10-03 DOI:10.1016/j.ijoes.2024.100820
Jun Yang , Yong Zhou , Fuan Yan , Baomin Fan , Yunxuan Wen
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Abstract

In order to understand the effect of drying-wetting alternation on the corrosion resistance of rusted weathering steel, firstly, a rusted weathering steel was obtaioned through the preparation of stabilized rust layer on the surface of naked weathering steel; secondly, a cyclic corrosion test (CCT) of drying-wetting alternation with different cyclic periods was carried out for rusted weathering steel. With the extension of cyclic period in drying-wetting CCT, the corrosion resistance of rusted weathering steel increased from 0 cycle to 6 cycle and then decreased after 6 cycle, which was closely associated with the variations of composition and microstructure for stabilized rust layer during the process of drying-wetting CCT. From 0 cycle to 6 cycle, the increased corrosion resistance of rusted weathering steel was attributed to the abundance rise of α-FeOOH in the interior of stabilized rust layer; however, from 6 cycle to 20 cycle, the decreased corrosion resistance of rusted weathering steel was due to the partial destruction of crystal sturcuture for stabilized rust layer.
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干燥-湿润交替对生锈耐候钢耐腐蚀性的影响
为了解干燥-湿润交变对锈蚀耐候钢耐蚀性的影响,首先通过在裸露耐候钢表面制备稳定锈层,获得了锈蚀耐候钢;其次,对锈蚀耐候钢进行了不同循环周期的干燥-湿润交变循环腐蚀试验(CCT)。随着干湿交替循环周期的延长,锈蚀耐候钢的耐蚀性从 0 个循环周期到 6 个循环周期均有所上升,6 个循环周期后又有所下降,这与干湿交替循环过程中稳定锈层的成分和微观结构变化密切相关。从 0 个周期到 6 个周期,锈化耐候钢的耐蚀性增加是由于稳定锈层内部的 α-FeOOH 丰度上升;而从 6 个周期到 20 个周期,锈化耐候钢的耐蚀性下降是由于稳定锈层的晶体结构部分破坏。
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来源期刊
CiteScore
3.00
自引率
20.00%
发文量
714
审稿时长
2.6 months
期刊介绍: International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry
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