Process Research and Mechanism Analysis of Pellet Roasting and Monazite Decomposition

IF 0.6 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Russian Journal of Non-Ferrous Metals Pub Date : 2024-10-19 DOI:10.1134/S1067821224600121
Jianfei Li, Yubo Xu, Zhisheng Dong, Ruifeng Ma, Xiaowei Zhang, Ligang Wen, Qing Wang, Xiaoyan Hao, Wenbin Xin, Zhaogang Liu
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Abstract

The concentrated sulfuric acid roasting method and caustic soda method, as the main processes for treating Bayan Obo mixed rare earth concentrate, have been operating normally for decades. However, due to their serious pollution, high cost, and waste of accompanying resources, relevant rare earth enterprises are facing severe environmental and cost pressures. The sodium carbonate roasting method is a clean method for treating rare earth minerals, but due to the phenomenon of “ring formation” in the rotary kiln during the reaction process, this process has not been widely promoted. Based on the above facts, this article proposes a decomposition method for sodium pelletizing to decompose monazite, which effectively alleviates the related technical problems caused by the “ring formation” problem. Moreover, the rare earth leaching rate is 86.87%, and the recovery rates of F, P, and Th are 98.64, 13.87, and 88.96%. It is a potential rare earth mineral cleaning production process and can provide certain technical references for relevant rare earth enterprises.

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颗粒焙烧和独居石分解的工艺研究与机理分析
浓硫酸焙烧法和烧碱法作为处理巴彦奥博混合稀土精矿的主要工艺,几十年来一直正常运行。然而,由于其污染严重、成本高昂、伴生资源浪费等问题,相关稀土企业正面临着严峻的环保和成本压力。碳酸钠焙烧法是一种清洁的稀土矿物处理方法,但由于在反应过程中回转窑内存在 "结圈 "现象,该工艺一直未得到广泛推广。基于上述事实,本文提出了一种钠法造粒分解独居石的方法,有效缓解了 "成环 "问题带来的相关技术难题。此外,稀土浸出率为 86.87%,F、P、Th 的回收率分别为 98.64%、13.87%、88.96%。这是一种有潜力的稀土矿物净化生产工艺,可为相关稀土企业提供一定的技术参考。
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来源期刊
Russian Journal of Non-Ferrous Metals
Russian Journal of Non-Ferrous Metals METALLURGY & METALLURGICAL ENGINEERING-
CiteScore
1.90
自引率
12.50%
发文量
59
审稿时长
3 months
期刊介绍: Russian Journal of Non-Ferrous Metals is a journal the main goal of which is to achieve new knowledge in the following topics: extraction metallurgy, hydro- and pirometallurgy, casting, plastic deformation, metallography and heat treatment, powder metallurgy and composites, self-propagating high-temperature synthesis, surface engineering and advanced protected coatings, environments, and energy capacity in non-ferrous metallurgy.
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