Polymeric membrane ion-selective electrode based on potential-modulated ion transfer: ultrasensitive measurement of oceanic pH†

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2024-10-21 Epub Date: 2024-10-22 DOI:10.1039/d4cc04807e
Lu Liu , Yuanxin Liu , Tianjia Jiang , Rongning Liang , Wei Qin
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Abstract

The application of a potentiometric pH electrode in ocean acidification observation is still a challenge due to its poor sensitivity to small pH changes. Herein, a simple approach to remarkably improve the detection precision of a polymeric membrane ion-selective electrode is proposed based on the potential-modulated ion transfer mechanism. The present sensing strategy displays highly sensitive responses to small pH changes for seawater analysis with a precision of 5 μpH, which is 2 orders of magnitude lower than that of the conventional pH electrode.

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基于电位调制离子转移的聚合物膜离子选择电极:超灵敏海洋 pH 值测量
由于电位pH电极对微小pH变化的灵敏度较低,因此将其应用于海洋酸化观测仍是一项挑战。本文提出了一种基于电位调制离子转移机制的简单方法,可显著提高聚合物膜离子选择电极的检测精度。本传感策略对海水分析中的微小 pH 值变化具有高度灵敏的响应,其精度为 5 µpH,比传统 pH 电极的精度低 2 个数量级。
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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