The CF3TMS adduct of anthraquinone as a monomer for making polymers with potential as separation membranes†

IF 3.9 2区 化学 Q2 POLYMER SCIENCE Polymer Chemistry Pub Date : 2024-10-02 Epub Date: 2024-10-21 DOI:10.1039/d4py01002g
Kim Jiayi Wu , John M. Tobin , Anli Ji , Yang Shi , Chunchun Ye , Gary S. Nichol , Alessio Fuoco , Mariagiulia Longo , Johannes C. Jansen , Neil B. McKeown
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Abstract

The readily prepared CF3TMS adduct of anthraquinone is shown to be an efficient monomer for superacid-catalysed step-growth polymerisations, as exemplified by its reaction with diphenyl ether. The resulting polymer () is produced rapidly, with high molecular mass, and shows promise as a gas separation membrane material.

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将蒽醌的 CF3TMS 加合物作为一种单体,用于制造具有分离膜潜力的聚合物
研究表明,易于制备的蒽醌 CF3TMS 加合物是超酸催化阶跃生长聚合反应的高效单体,其与二苯醚的反应就是一个例子。由此产生的聚合物(BTFMA-DPE)生成迅速,分子质量高,有望用作气体分离膜材料。
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来源期刊
Polymer Chemistry
Polymer Chemistry POLYMER SCIENCE-
CiteScore
8.60
自引率
8.70%
发文量
535
审稿时长
1.7 months
期刊介绍: Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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