Kim Jiayi Wu, John M. Tobin, Anli Ji, Yang Shi, Chunchun Ye, Gary S. Nichol, Alessio Fuoco, Mariagiulia Longo, Johannes C. Jansen, Neil B. McKeown
{"title":"The CF3TMS adduct of anthraquinone as a monomer for making polymers with potential as separation membranes","authors":"Kim Jiayi Wu, John M. Tobin, Anli Ji, Yang Shi, Chunchun Ye, Gary S. Nichol, Alessio Fuoco, Mariagiulia Longo, Johannes C. Jansen, Neil B. McKeown","doi":"10.1039/d4py01002g","DOIUrl":null,"url":null,"abstract":"The readily prepared CF<small><sub>3</sub></small>TMS adduct of anthraquinone is shown to be an efficient monomer for superacid-catalysed step-growth polymerisations, as exemplified by its reaction with diphenyl ether. The resulting polymer (<strong>BTFMA-DPE</strong>) is produced rapidly, with high molecular mass, and shows promise as a gas separation membrane material.","PeriodicalId":100,"journal":{"name":"Polymer Chemistry","volume":null,"pages":null},"PeriodicalIF":4.1000,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4py01002g","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
The readily prepared CF3TMS adduct of anthraquinone is shown to be an efficient monomer for superacid-catalysed step-growth polymerisations, as exemplified by its reaction with diphenyl ether. The resulting polymer (BTFMA-DPE) is produced rapidly, with high molecular mass, and shows promise as a gas separation membrane material.
期刊介绍：
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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