Raffaele Marzocchi, Ilaria Grimaldi, Odda Ruiz de Ballesteros, Giuseppe Femina, Adriano Guida, Rosa Ricciardi, Pasquale Morvillo, Carmine Capacchione, Finizia Auriemma
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引用次数: 0
Abstract
The structure-properties relationships of sustainable materials derived from biomass-based monomers are investigated, focusing on hybrid styrene/terpene-based copolymers with blocky microstructures, such as β-myrcene- and β-ocimene-styrene copolymers. The samples show complex glass transition dynamics, as evidenced by the physical aging experienced by the amorphous phase in styrene-rich copolymers. The tendency of styrene- and terpene-rich sequences to give heterogeneous morphologies with correlation strength extending over 10-40 nm is outlined, through small-angle X-ray scattering analysis. A new class of terpene-based hybrid systems, holding promise for applications in surface coating technologies, is identified.
期刊介绍：
Macromolecular Rapid Communications publishes original research in polymer science, ranging from chemistry and physics of polymers to polymers in materials science and life sciences.
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