Rational design of an isatin-based colorimetric and solvatochromic receptor for carbonate ions and its application in molecular-scale logic gates & memory units.

Abstract

A simple and highly sensitive isatin-based colorimetric sensor ISAT 3(a-d) was synthesized through a single-step reaction. The as-prepared receptor ISAT 3b with carbonate ions (CO₃^2- ions) shows a significant red shift in the UV-visible absorption spectra and a visible color change from pale yellow to pink. Also, the receptor ISAT 3b shows unique solvatochromic behavior with CO₃^2- ions in different aprotic solvents and solvent compositions. Moreover, the receptor's pink coloration (absorption maxima at 544 nm) with CO₃^2- ions could be reversible by adding HSO₄^- ions (attain initial pale-yellow color, absorption maxima at 425 nm), which can be repeatable. The observed color changes with spectral shift and reversibility of the receptor with CO₃^2- ions and HSO₄^- ions provide "ON-OFF" switching for applying molecular logic gates. Receptors exhibited properties, such as reversibility and repeatability, benefit the design of a molecular-scale sequential memory unit with a display of "Writing-Reading-Erasing-Reading". The real sample analysis was also carried out to prove the practical applicability of receptor (ISAT 3b) for detecting CO₃^2- ions.