Enhanced optical nonlinearity in suspensions of dual-resonance gold–copper chalcogenide core–shell nanoparticles

IF 3.5 2区 物理与天体物理 Q2 PHYSICS, APPLIED Applied Physics Letters Pub Date : 2024-10-21 DOI:10.1063/5.0225508
Dongling Ning, Xinyu Lin, Yu-Xuan Ren, Yi Liang, Tao Lin
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Abstract

Plasmonic copper chalcogenide (Cu2−xE, E = S, Se, Te) nanoparticles (NPs) possess high potentials in photothermal therapy and photoacoustic tomography for their unique localized surface plasmon resonant absorption in the second near-infrared biologically transparent window. In this study, strong thermal-induced nonlinear negative-lens effect in aqueous suspensions containing Cu2−xSe NPs was observed. Furthermore, the nonlinear absorption was notably enhanced in aqueous suspensions containing Au@Cu2−xSe core–shell NPs, as the positive nonlinear absorption coefficient increased by 20-fold, attributed to the strong plasmonic coupling in Au@Cu2−xSe core–shell NPs. This finding underscores the importance of the nonlinear optical behaviors of plasmonic NPs in biomedical applications, as they offer extra strategy for optimizing systems and incorporating additional functionalities.
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双共振金铜共卤化物核壳纳米粒子悬浮液中增强的光学非线性
等离子体铜铅化物(Cu2-xE,E = S、Se、Te)纳米粒子(NPs)在第二近红外生物透明窗口具有独特的局部表面等离子体共振吸收,因此在光热治疗和光声层析成像方面具有很高的潜力。本研究在含有 Cu2-xSe NPs 的水悬浮液中观察到了强烈的热诱导非线性负透镜效应。此外,在含有 Au@Cu2-xSe 核壳 NPs 的水悬浮液中,非线性吸收显著增强,正非线性吸收系数增加了 20 倍,这归因于 Au@Cu2-xSe 核壳 NPs 中的强等离子耦合。这一发现强调了质子 NPs 的非线性光学行为在生物医学应用中的重要性,因为它们为优化系统和整合附加功能提供了额外的策略。
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来源期刊
Applied Physics Letters
Applied Physics Letters 物理-物理:应用
CiteScore
6.40
自引率
10.00%
发文量
1821
审稿时长
1.6 months
期刊介绍: Applied Physics Letters (APL) features concise, up-to-date reports on significant new findings in applied physics. Emphasizing rapid dissemination of key data and new physical insights, APL offers prompt publication of new experimental and theoretical papers reporting applications of physics phenomena to all branches of science, engineering, and modern technology. In addition to regular articles, the journal also publishes invited Fast Track, Perspectives, and in-depth Editorials which report on cutting-edge areas in applied physics. APL Perspectives are forward-looking invited letters which highlight recent developments or discoveries. Emphasis is placed on very recent developments, potentially disruptive technologies, open questions and possible solutions. They also include a mini-roadmap detailing where the community should direct efforts in order for the phenomena to be viable for application and the challenges associated with meeting that performance threshold. Perspectives are characterized by personal viewpoints and opinions of recognized experts in the field. Fast Track articles are invited original research articles that report results that are particularly novel and important or provide a significant advancement in an emerging field. Because of the urgency and scientific importance of the work, the peer review process is accelerated. If, during the review process, it becomes apparent that the paper does not meet the Fast Track criterion, it is returned to a normal track.
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