Sulfonated Covalent Organic Frameworks Anchoring Cobalt as High-Efficient and Stable Catalysts for Peroxymonosulfate Activation.

Abstract

Heterogeneous cobalt-based catalysts are highly effective in activing peroxymonosulfate (PMS) and produce free radicals to deal with recalcitrant organic pollutants in water. However, unfeasible recyclability and gradual performance degradation remain challenging due to the easy agglomeration and leaching of active cobalt species. Herein, a strategy is proposed to construct stably anchored and highly dispersed Co²⁺ sites on dual functional sulfonated covalent organic frameworks (COF-Co). The sulfonic acid groups are able to realize the targeted binding with cobalt ions through a two-step cation-exchange method, leading to strong combination with active Co²⁺ sites and utmost utilization efficiencies. Moreover, the super-hydrophility of sulfonic acid groups favors the rapid accessibility of organic molecules to the catalyst and accelerates the degradation. Remarkably, COF-Co exhibits high activity in PMS activation, effective oxidation for tetracycline degradation (92% within 30 min at 30 mg L^-1) and other coloring contaminants, and excellent recycle stability. This work can guide the rational design of efficient and environmentally friendly PMS-activated catalyst with great potential for application in wastewater treatment.