M. B. Gazizov, R. A. Khairullin, S. Yu. Ivanova, R. F. Karimova, B. D. Nuriakhmetov, O. D. Khairullina, L. R. Shaikhutdinova, N. N. Gazizova
{"title":"Reactions of phosphorus (iv) and orthocarboxylic acid esters with benzal and benzyl halides: pathways and catalysis","authors":"M. B. Gazizov, R. A. Khairullin, S. Yu. Ivanova, R. F. Karimova, B. D. Nuriakhmetov, O. D. Khairullina, L. R. Shaikhutdinova, N. N. Gazizova","doi":"10.1007/s11172-024-4382-8","DOIUrl":null,"url":null,"abstract":"<div><p>The main pathway of the reaction of benzal and benzyl halides with phosphorus(<span>iv</span>) acid esters followed the dehalophosphonyl/phosphinyl(oxylation) course and led to the corresponding carbonyl-containing compounds or benzyl esters. A new reaction between α-chloro ethers and <i>O</i>-alkyl diethylphosphinates was discovered. The reactions of benzyl halides with esters of phosphorus(<span>iv</span>) and orthocarboxylic acids were catalyzed by anhydrous zinc chloride.</p></div>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":"73 9","pages":"2693 - 2700"},"PeriodicalIF":1.7000,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11172-024-4382-8","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The main pathway of the reaction of benzal and benzyl halides with phosphorus(iv) acid esters followed the dehalophosphonyl/phosphinyl(oxylation) course and led to the corresponding carbonyl-containing compounds or benzyl esters. A new reaction between α-chloro ethers and O-alkyl diethylphosphinates was discovered. The reactions of benzyl halides with esters of phosphorus(iv) and orthocarboxylic acids were catalyzed by anhydrous zinc chloride.
期刊介绍：
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.
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