{"title":"Photochemically induced synthesis of a [PtIV(C^C*)(acac)Cl(CXCl2)] X = H, D complex","authors":"Felix Wurl, Sergej Stipurin, Thomas Strassner","doi":"10.1016/j.jorganchem.2024.123306","DOIUrl":null,"url":null,"abstract":"<div><div>Addition of the solvent to a cyclometalated <em>N</em>-heterocyclic carbene (NHC) platinum(II) complex at room temperature in chloroform (CHCl<sub>3</sub>)/deuterochloroform (CDCl<sub>3</sub>) solution when irradiated with blue light yields a new class of platinum(IV) complexes. The <em>trans</em>-addition corresponds to the thermodynamically favoured product according to density functional theory calculations (PBE0(D3)/def2-tzvpp) which predict the <em>cis</em>-isomer to be energetically disfavoured. The complex is also characterized using single crystal diffraction thereby unambiguously confirming the reported structure.</div></div>","PeriodicalId":374,"journal":{"name":"Journal of Organometallic Chemistry","volume":"1022 ","pages":"Article 123306"},"PeriodicalIF":2.1000,"publicationDate":"2024-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Organometallic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022328X24003012","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Addition of the solvent to a cyclometalated N-heterocyclic carbene (NHC) platinum(II) complex at room temperature in chloroform (CHCl3)/deuterochloroform (CDCl3) solution when irradiated with blue light yields a new class of platinum(IV) complexes. The trans-addition corresponds to the thermodynamically favoured product according to density functional theory calculations (PBE0(D3)/def2-tzvpp) which predict the cis-isomer to be energetically disfavoured. The complex is also characterized using single crystal diffraction thereby unambiguously confirming the reported structure.
期刊介绍：
The Journal of Organometallic Chemistry targets original papers dealing with theoretical aspects, structural chemistry, synthesis, physical and chemical properties (including reaction mechanisms), and practical applications of organometallic compounds.
Organometallic compounds are defined as compounds that contain metal - carbon bonds. The term metal includes all alkali and alkaline earth metals, all transition metals and the lanthanides and actinides in the Periodic Table. Metalloids including the elements in Group 13 and the heavier members of the Groups 14 - 16 are also included. The term chemistry includes syntheses, characterizations and reaction chemistry of all such compounds. Research reports based on use of organometallic complexes in bioorganometallic chemistry, medicine, material sciences, homogeneous catalysis and energy conversion are also welcome.
The scope of the journal has been enlarged to encompass important research on organometallic complexes in bioorganometallic chemistry and material sciences, and of heavier main group elements in organometallic chemistry. The journal also publishes review articles, short communications and notes.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
