Natural Surface Frustrated Lewis Pairs: The Concept and Beyond.

IF 3.5 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemistry - An Asian Journal Pub Date : 2024-10-31 DOI:10.1002/asia.202401155
Xi-Yang Yu, Xue Su, Meng-Jia Xi, Zheng-Qing Huang, Chun-Ran Chang
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Abstract

The reusable and separable surface frustrated Lewis pairs (SFLPs) open up a novel approach to efficient small-molecule activation and conversion in heterogeneous catalysis. However, SFLPs have only been reported on limited systems due to the difficulty in the design and synthesis process. The inherent Lewis pairs on various solid materials offer promising opportunities for finding natural SFLPs, providing a straightforward and efficient strategy to overcome the current limitations. In this concept, we retrospect the concept of natural SFLPs proposed on wurtzite crystal surfaces and identify other natural SFLPs that probably exist on solid materials, including reduced oxide surfaces, corrugated graphene, and perovskite quantum dots. Having focused on the reactivity of natural SFLPs in small-molecule activation, we discuss the current challenges, propose possible research directions, and highlight potential applications of natural SFLPs in heterogeneous catalysis.

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自然表面受挫路易斯对:概念及其他
可重复使用且可分离的表面受挫路易斯对(SFLPs)为异相催化中高效的小分子活化和转化开辟了一条新途径。然而,由于设计和合成过程的困难,SFLPs 只在有限的体系中得到报道。各种固体材料上固有的路易斯对为寻找天然 SFLPs 提供了很好的机会,为克服目前的局限性提供了一种直接有效的策略。在这一概念中,我们回顾了在沃特兹晶体表面提出的天然 SFLPs 概念,并确定了固体材料上可能存在的其他天然 SFLPs,包括还原氧化物表面、波纹石墨烯和过氧化物量子点。在重点研究了天然 SFLPs 在小分子活化中的反应性之后,我们讨论了当前面临的挑战,提出了可能的研究方向,并强调了天然 SFLPs 在异相催化中的潜在应用。
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来源期刊
Chemistry - An Asian Journal
Chemistry - An Asian Journal 化学-化学综合
CiteScore
7.00
自引率
2.40%
发文量
535
审稿时长
1.3 months
期刊介绍: Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics. Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews. A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal. Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).
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