{"title":"Silyl Radical-Participated Silylfunctionalization of Alkenes and Alkynes","authors":"Yang Zheng, Yi-Jie Zhu, Yi-Nan Zhang, Fei Chen","doi":"10.1002/ejoc.202401018","DOIUrl":null,"url":null,"abstract":"Alkenes and alkynes are inexpensive and readily available basic chemicals. Silyl radical-participated silylation of alkenes and alkynes provides a powerful tool for the direct construction of organosilicon compounds. Compared to hydrosilylation reactions, silylfunctionalization reactions are more attractive and advantageous in building diverse organosilicon compounds, which has led to their becoming a research focus in organic synthesis. Herein, we provide a comprehensive overview of recent advances in silyl radical-participated silylfunctionalization of alkenes and alkynes.","PeriodicalId":167,"journal":{"name":"European Journal of Organic Chemistry","volume":"319 1","pages":""},"PeriodicalIF":2.5000,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Organic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/ejoc.202401018","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
Alkenes and alkynes are inexpensive and readily available basic chemicals. Silyl radical-participated silylation of alkenes and alkynes provides a powerful tool for the direct construction of organosilicon compounds. Compared to hydrosilylation reactions, silylfunctionalization reactions are more attractive and advantageous in building diverse organosilicon compounds, which has led to their becoming a research focus in organic synthesis. Herein, we provide a comprehensive overview of recent advances in silyl radical-participated silylfunctionalization of alkenes and alkynes.
期刊介绍：
The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry:
Liebigs Annalen
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry.
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