Tim David , Robert Oestreich , Tobias Pausch , Yuki Wada , Tom Fleck-Kunde , Masaki Kawano , Christoph Janiak , Bernd M. Schmidt
{"title":"Fluorinated vs. non-fluorinated tetrahedral Tri4Tri4 porous organic cages for H2, CO2, and CH4 adsorption†","authors":"Tim David , Robert Oestreich , Tobias Pausch , Yuki Wada , Tom Fleck-Kunde , Masaki Kawano , Christoph Janiak , Bernd M. Schmidt","doi":"10.1039/d4cc05277c","DOIUrl":null,"url":null,"abstract":"<div><div>We present the synthesis of two porous complementary tetrahedral Tri<sup>4</sup>Tri<sup>4</sup> imine cages, exhibiting Brunauer–Emmett–Teller (BET) surface areas of 591 m<sup>2</sup> g<sup>−1</sup> and 753 m<sup>2</sup> g<sup>−1</sup>, suitable for the adsorption of H<sub>2</sub>, CO<sub>2</sub>, and CH<sub>4</sub>. Comparisons in terms of crystallinity, thermal stability, porosity, and selectivity highlight the promising properties of fluorinated and non-fluorinated porous organic cages as functional materials.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"60 99","pages":"Pages 14762-14765"},"PeriodicalIF":4.2000,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/cc/d4cc05277c?page=search","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734524024364","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/11/6 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
We present the synthesis of two porous complementary tetrahedral Tri4Tri4 imine cages, exhibiting Brunauer–Emmett–Teller (BET) surface areas of 591 m2 g−1 and 753 m2 g−1, suitable for the adsorption of H2, CO2, and CH4. Comparisons in terms of crystallinity, thermal stability, porosity, and selectivity highlight the promising properties of fluorinated and non-fluorinated porous organic cages as functional materials.
期刊介绍:
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