Enhanced Dual-Emission Properties of Mn-Doped CsPbCl3/ZIF-8 Nanocomposites for Display

IF 5.3 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY ACS Applied Nano Materials Pub Date : 2024-10-24 DOI:10.1021/acsanm.4c0492810.1021/acsanm.4c04928
Niu Lai, Guangsheng Liu, Yuewei Li, Yanqiong Yang, Maoxin He, Shaoqi Hou, Steven J. Langford, Jiayan Liao*, Yu Yang* and Rongfei Wang*, 
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Abstract

Mn-doped CsPbX3 quantum dots (QDs) are recognized for their dual-emission characteristics and low lead content, making them valuable in display applications. In this study, dual-emission peaks at 406 and 589 nm were achieved in Mn-doped CsPbCl3 QDs through a high-temperature thermal injection method. The 406 nm peak is sourced from the QD host, while the 589 nm peak results from Mn doping. Enhancement of both emission peaks is observed when Mn-doped QDs are integrated with ZIF-8 material via in situ growth, leading to a greater than 3-fold increase in emission intensity. The resulting composite material demonstrates considerable stability, retaining over 40% intensity under UV light, 50% under continuous heating at 100 °C, and 44% in air exposure after 25 days. These results highlight the potential of nanomaterials for high-performance optoelectronic devices.

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用于显示器的掺锰 CsPbCl3/ZIF-8 纳米复合材料的增强双发射特性
掺锰的 CsPbX3 量子点(QDs)因其双发射特性和低铅含量而被公认为在显示应用中具有重要价值。在这项研究中,通过高温热注入方法,掺锰 CsPbCl3 量子点实现了 406 纳米和 589 纳米的双发射峰。406 nm 的峰值来自 QD 主晶,而 589 nm 的峰值则来自掺杂的锰。当掺杂锰的 QD 通过原位生长与 ZIF-8 材料结合时,两个发射峰都会增强,使发射强度增加 3 倍以上。由此产生的复合材料具有相当高的稳定性,在紫外线照射下能保持 40% 以上的强度,在 100 °C 持续加热下能保持 50% 的强度,在空气中暴露 25 天后能保持 44% 的强度。这些结果凸显了纳米材料在高性能光电器件方面的潜力。
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来源期刊
CiteScore
8.30
自引率
3.40%
发文量
1601
期刊介绍: ACS Applied Nano Materials is an interdisciplinary journal publishing original research covering all aspects of engineering, chemistry, physics and biology relevant to applications of nanomaterials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important applications of nanomaterials.
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