Li-Jun Zhai , Cui-Hong Zhang , Jiang Li , Miao Liu , Lan-Qing Hao
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引用次数: 0
Abstract
One discrete 3d-4f adduct with formula {[Cu(hfac)(Nit-PhCH2-PyN)]+[Dy(hfac)4]–} (hfac=hexafluoroacetylacetonate, Nit-PhCH2-PyN=2-[4-[bi(2-pyridylmethyl)amine]-tolyl]-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) has been afforded on the basis of a one-pot process of Dy(hfac)3·2H2O, Cu(hfac)2·2H2O and a tridentate chelate ligand Nit-PhCH2-PyN. Interestingly, one discrete [Dy(hfac)4]– anion and [Cu(hfac)(Nit-PhCH2-PyN)]+ serving as the counter-ion are present in the 3d-4f complex. In addition, magnetic studies have shown field-induced slow magnetic relaxation is derived from the [Dy(hfac)4]– anion, involving the eight-coordinated DyIII ion with D4d symmetry.
期刊介绍：
Inorganica Chimica Acta is an established international forum for all aspects of advanced Inorganic Chemistry. Original papers of high scientific level and interest are published in the form of Articles and Reviews.
Topics covered include:
• chemistry of the main group elements and the d- and f-block metals, including the synthesis, characterization and reactivity of coordination, organometallic, biomimetic, supramolecular coordination compounds, including associated computational studies;
• synthesis, physico-chemical properties, applications of molecule-based nano-scaled clusters and nanomaterials designed using the principles of coordination chemistry, as well as coordination polymers (CPs), metal-organic frameworks (MOFs), metal-organic polyhedra (MPOs);
• reaction mechanisms and physico-chemical investigations computational studies of metalloenzymes and their models;
• applications of inorganic compounds, metallodrugs and molecule-based materials.
Papers composed primarily of structural reports will typically not be considered for publication.
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