Cavern integrity under cyclic underground hydrogen storage in heterogeneous Brazilian pre-salt formations

IF 8.1 2区 工程技术 Q1 CHEMISTRY, PHYSICAL International Journal of Hydrogen Energy Pub Date : 2024-11-16 DOI:10.1016/j.ijhydene.2024.11.152
Williams Dias , Cristian Mejia , Deane Roehl (Corresponding author)
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Abstract

Transitioning to cleaner energy sources is crucial for mitigating carbon dioxide emissions and addressing global energy challenges. Hydrogen has emerged as a solution, particularly due to its versatile applications in energy storage and generation. This research focuses on the hydrogen storage process in the Brazilian pre-salt caverns. It is motivated by its favorable characteristics, such as low permeability, creep behavior, self-healing, and competitive cost of salt caverns compared to other repositories. Hydrogen thermodynamics follows a diabatic solution that updates gas temperature and pressure in real time through a link between the CoolProp library and the in-house multiphysics and multiscale framework GeMA. Moreover, the research incorporates salt heterogeneities based on the well-log data from the Tupi field, providing a more accurate representation of Brazilian pre-salt field conditions and how different salt layers may affect the overall system. This approach allows for a comprehensive analysis of the cavern's response to hydrogen injection/discharge cycles, addressing both thermodynamic factors and geological variabilities often neglected by previous studies. The results demonstrated that salt rock heterogeneities may potentialize the extension of the zone with compromised integrity and induce significant permeability changes. It also offers valuable insights into the specific behavior of each type of salt rock during the hydrogen cyclic storage process.

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巴西盐前异质地层循环地下储氢条件下的岩洞完整性
向清洁能源过渡对于减少二氧化碳排放和应对全球能源挑战至关重要。氢已成为一种解决方案,特别是由于其在能源储存和发电方面的广泛应用。这项研究的重点是巴西盐前岩洞中的氢储存过程。这是因为盐洞具有低渗透性、蠕变行为、自愈性等有利特性,而且与其他储存库相比,盐洞的成本具有竞争力。氢气热力学遵循一种非饱和解决方案,通过 CoolProp 库与内部多物理场和多尺度框架 GeMA 之间的链接,实时更新气体温度和压力。此外,研究还根据图皮油田的井记录数据纳入了盐的异质性,更准确地反映了巴西前盐田的条件以及不同盐层可能对整个系统产生的影响。通过这种方法,可以全面分析岩洞对注氢/放氢循环的反应,解决以往研究经常忽略的热力学因素和地质变化问题。研究结果表明,盐岩的异质性可能会使完整性受损的区域扩展,并引起显著的渗透性变化。该研究还为了解各类盐岩在氢气循环存储过程中的具体行为提供了宝贵的见解。
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来源期刊
International Journal of Hydrogen Energy
International Journal of Hydrogen Energy 工程技术-环境科学
CiteScore
13.50
自引率
25.00%
发文量
3502
审稿时长
60 days
期刊介绍: The objective of the International Journal of Hydrogen Energy is to facilitate the exchange of new ideas, technological advancements, and research findings in the field of Hydrogen Energy among scientists and engineers worldwide. This journal showcases original research, both analytical and experimental, covering various aspects of Hydrogen Energy. These include production, storage, transmission, utilization, enabling technologies, environmental impact, economic considerations, and global perspectives on hydrogen and its carriers such as NH3, CH4, alcohols, etc. The utilization aspect encompasses various methods such as thermochemical (combustion), photochemical, electrochemical (fuel cells), and nuclear conversion of hydrogen, hydrogen isotopes, and hydrogen carriers into thermal, mechanical, and electrical energies. The applications of these energies can be found in transportation (including aerospace), industrial, commercial, and residential sectors.
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