In-situ preparation of CeO2@MIL-88B nanocomposite for improving “turn-on” fluorescent sensing toward Thiabendazole

IF 8.5 1区 农林科学 Q1 CHEMISTRY, APPLIED Food Chemistry Pub Date : 2024-11-19 DOI:10.1016/j.foodchem.2024.142148
Yan Fan, Bo Hou, Fang Lu, Dao Liu, Xiang Cui
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Abstract

A novel “turn-on” fluorescent sensor of CeO2@MIL-88B was constructed successfully via the facile in-situ strategy. The as-obtained CeO2@MIL-88B could be used for effectively detecting the analyte of thiabendazole (TBZ) by luminescence enhancement, which limit of detection (LOD) was as low as 0.294 μM (nearly 10.4 times smaller than that of MIL-88B). The detection behavior for TBZ exhibited the excellent selectivity and anti-interference ability. Systematic explorations were performed to shed light on the underlying mechanism of “turn-on” effect on fluorescence after adding TBZ. Moreover, the CeO2@MIL-88B was also employed for the determination of TBZ in the real samples of orange and cucumber.

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原位制备 CeO2@MIL-88B 纳米复合材料,提高噻苯咪唑的 "开启 "荧光传感能力
通过简便的原位策略,成功构建了一种新型的 "开启式 "CeO2@MIL-88B荧光传感器。得到的 CeO2@MIL-88B 可通过发光增强有效地检测噻苯咪唑(TBZ),其检测限低至 0.294 μM(比 MIL-88B 小近 10.4 倍)。对 TBZ 的检测表现出了极佳的选择性和抗干扰能力。对加入 TBZ 后荧光 "开启 "效应的内在机制进行了系统的探索。此外,还利用 CeO2@MIL-88B 测定了橘子和黄瓜实际样品中的 TBZ。
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来源期刊
Food Chemistry
Food Chemistry 工程技术-食品科技
CiteScore
16.30
自引率
10.20%
发文量
3130
审稿时长
122 days
期刊介绍: Food Chemistry publishes original research papers dealing with the advancement of the chemistry and biochemistry of foods or the analytical methods/ approach used. All papers should focus on the novelty of the research carried out.
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