Effect of Coal Spontaneous Combustion Gases on the Laminar Burning Velocity of the CH4/Air Premixed Flame

Fuchao Tian, Yuntao Liang, Mengmeng Luo, Kai Wang, Wen Zeng and Yu Liu*, 
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Abstract

In order to investigate the effect of coal spontaneous combustion (CSC) gases such as CO, C2H4, C2H6, C3H8, C2H2, and H2 on the laminar burning velocity (LBV) of the CH4/air premixed flame, a constant volume chamber and a high-speed camera were used to measure the LBV of a 90% (in vol) CH4 and 10% CSC gas mixed fuel at an initial temperature of 300 K and over a wide equivalence ratio range from 0.7 to 1.3. Results show that the addition of all the CSC gases increases the LBV of CH4. Among all CSC gases, the CH4/C2H2 mixed fuel has the highest LBV, and the CH4/CO mixed fuel has the lowest LBV. With the addition of three typical stages of CSC gases, the LBV of CH4 was significantly enhanced. Based on the reaction path, mole fraction, and rate of production analysis, it is found that the addition of CSC gases in Stage 2 can increase the concentration of C2H5 and the consumption rate in the CH3–C2H6–C2H5 path, which is different from Stages 1 and 3. In addition, all the concentrations of H, O, and OH free radicals increase with the addition of three typical stages of CSC gases.

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煤炭自燃气体对甲烷/空气预混合火焰层状燃烧速度的影响
为了研究 CO、C2H4、C2H6、C3H8、C2H2 和 H2 等煤自燃(CSC)气体对 CH4/空气预混合火焰层燃速度(LBV)的影响,我们使用恒容室和高速照相机测量了初始温度为 300 K、等效比范围为 0.7 至 1.3 的 90% (体积分数)CH4 和 10% CSC 气体混合燃料的 LBV。结果表明,添加所有 CSC 气体都会增加 CH4 的枸杞多糖伏。在所有 CSC 气体中,CH4/C2H2 混合燃料的 LBV 最高,CH4/CO 混合燃料的 LBV 最低。添加三个典型阶段的 CSC 气体后,CH4 的 LBV 显著提高。根据反应路径、摩尔分数和生成速率分析发现,在第二阶段添加 CSC 气体可提高 C2H5 的浓度和 CH3-C2H6-C2H5 路径的消耗速率,这与第一和第三阶段不同。此外,随着三个典型阶段 CSC 气体的加入,H、O 和 OH 自由基的浓度均有所增加。
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