Visible-light-induced hydrosulfonylation of alkynes driven by electron-donor–acceptor (EDA) complexes

IF 1.5 4区 化学 Q3 CHEMISTRY, ORGANIC Tetrahedron Letters Pub Date : 2024-11-16 DOI:10.1016/j.tetlet.2024.155368
Xiao-De An , Hui-Yun Wang , Long-Xue Wang , Wen-Tao Jiang , Jia-Jun Xu , Qing-Quan Sheng , Qixue Qin , Ying Fu
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Abstract

The method toward the vinyl sulfones has been realized by visible-light-induced hydrosulfonylation of alkynes via an EDA process. DIPEA was used as both electron donor for EDA complex and hydrogen donor for hydrogen atom transfer.

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电子供体-受体(EDA)复合物驱动的可见光诱导的炔烃氢磺化反应
这种乙烯基砜的制备方法是通过 EDA 过程在可见光诱导下对炔烃进行氢磺酰化而实现的。DIPEA 既是 EDA 复合物的电子供体,也是氢原子转移的氢供体。
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来源期刊
Tetrahedron Letters
Tetrahedron Letters 化学-有机化学
CiteScore
3.50
自引率
5.60%
发文量
521
审稿时长
28 days
期刊介绍: Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.
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