Ligand and Metal Effects in the Gas-Phase Fragmentation of Thiomethoxymethyl Complexes

IF 2.2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR European Journal of Inorganic Chemistry Pub Date : 2024-11-22 DOI:10.1002/ejic.202483202
Gilles Stebens, David Kury, Lukas Jakob, Burkhard Butschke
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Abstract

The Cover Feature illustrates the uneven fight between our gaseous hero Gas-Face (“He He He”) and the evil PP-Pig-Man “coordinating” cationic PtII-thiomethoxymethyl complexes. By virtue of Gas-Face′s superpower—to be everywhere—collisions of the (PP-Pig-Man-)diphospine complexes with helium cause their gas-phase fragmentation. Depending on the bite angle, different neutrals are lost: while neutral dimethylsulfide is preferentially ejected for bite angles >90° (here dPPb), the loss of ethene and thioformaldehyde dominates for bite angles <90° (here dPPm). More information can be found in the Research Article by B. Butschke and co-workers.

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硫代甲氧基甲基络合物气相碎片中的配体和金属效应
封面特写展示了气态英雄 Gas-Face("他他他")与 "协调 "阳离子 PtII-硫代甲氧基甲基络合物的邪恶 PP-Pig-Man 之间的不均衡斗争。由于 "气-脸 "的超能力--无处不在--(PP-猪-人)二磷酸络合物与氦的碰撞导致其气相碎裂。根据咬合角度的不同,会损失不同的中性物质:咬合角度为 90°(此处为 dPPb)时,中性二甲基硫化物会优先喷出,而咬合角度为 90°(此处为 dPPm)时,则主要损失乙烯和硫代甲醛。更多信息,请参阅 B. Butschke 及其合作者的研究文章。
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来源期刊
European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
4.30
自引率
4.30%
发文量
419
审稿时长
1.3 months
期刊介绍: The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.
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