Thermally activated sensitization of organics by lanthanide complexes for near-infrared photochemical upconversion†

IF 2.7 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY New Journal of Chemistry Pub Date : 2024-11-05 DOI:10.1039/D4NJ04586F
Ling Zhang, Guohua Zhu, Rui Hu, Guoqiang Yang, Jinping Chen, Tianjun Yu, Yi Li and Yi Zeng
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Abstract

A series of solid-state triplet–triplet annihilation upconversion systems have been developed utilizing a penta-nuclear Yb complex as the sensitizer, converting near-infrared light into blue, green and red photons. The endothermic sensitization of organic annihilators by the Yb complex enables an anti-Stokes shift exceeding 1.3 eV.

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镧系配合物对有机物的热激活敏化,实现近红外光化学上转换†。
我们开发了一系列固态三重-三重湮灭上转换系统,利用五核镱复合物作为敏化剂,将近红外光转换成蓝、绿和红光子。镱络合物对有机湮灭体的内热敏化使反斯托克斯位移超过 1.3 eV。
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来源期刊
New Journal of Chemistry
New Journal of Chemistry 化学-化学综合
CiteScore
5.30
自引率
6.10%
发文量
1832
审稿时长
2 months
期刊介绍: A journal for new directions in chemistry
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