New 5,6-dihydro pyrimidin-2(1H)-thione compound containing imine moiety: synthesis, characterization, and nonlinear optical study

IF 2.8 4区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Journal of Materials Science: Materials in Electronics Pub Date : 2024-12-09 DOI:10.1007/s10854-024-13975-6
Jenan Al Ameri, H. A. Sultan, Mariam Abdul-Bary, Qusay M. A. Hassan, Batool Haddad, C. A. Emshary
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Abstract

A novel chemical, 5,6-dihydro pyrimidin-2(1H)-thione (compound A), is synthesized and characterized using several analytical techniques including FTIR, 1H NMR, 13CNMR, and mass spectroscopies. The compound’s structure has been determined. The nonlinear optical (NLO) properties of the compound are analyzed by subjecting it to visible continuous wave (cw), low power laser beams and observing the effects through the Z-scan and diffraction patterns. The initial approach yielded a nonlinear refractive index (NLRI) of 0.21 × 10−7 cm2/W, while the following method yielded an NLRI of 3.925 × 10−7 cm2/W. Each optical switching utilizes two laser beams: one beam controlled at a wavelength of 532 nm and another beam controlling at a wavelength of 473 nm.

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新的含亚胺基团的5,6-二氢嘧啶-2(1H)-硫酮化合物:合成、表征和非线性光学研究
合成了一种新型化合物,5,6-二氢嘧啶-2(1H)-硫酮(化合物A),并利用FTIR、1H NMR、13CNMR和质谱等分析技术对其进行了表征。这种化合物的结构已经确定了。将该化合物置于可见连续波、低功率激光束下,并通过z扫描和衍射图观察其非线性光学特性。初始方法的非线性折射率为0.21 × 10−7 cm2/W,而后续方法的非线性折射率为3.925 × 10−7 cm2/W。每个光开关使用两束激光:一束控制在波长532纳米,另一束控制在波长473纳米。
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来源期刊
Journal of Materials Science: Materials in Electronics
Journal of Materials Science: Materials in Electronics 工程技术-材料科学:综合
CiteScore
5.00
自引率
7.10%
发文量
1931
审稿时长
2 months
期刊介绍: The Journal of Materials Science: Materials in Electronics is an established refereed companion to the Journal of Materials Science. It publishes papers on materials and their applications in modern electronics, covering the ground between fundamental science, such as semiconductor physics, and work concerned specifically with applications. It explores the growth and preparation of new materials, as well as their processing, fabrication, bonding and encapsulation, together with the reliability, failure analysis, quality assurance and characterization related to the whole range of applications in electronics. The Journal presents papers in newly developing fields such as low dimensional structures and devices, optoelectronics including III-V compounds, glasses and linear/non-linear crystal materials and lasers, high Tc superconductors, conducting polymers, thick film materials and new contact technologies, as well as the established electronics device and circuit materials.
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