Tri-phenyl-phospho-nium tri-chlorido-(tri-phenyl-phosphane-κP)cobaltate(II) benzene disolvate.

IUCrData Pub Date : 2024-11-22 eCollection Date: 2024-11-01 DOI:10.1107/S2414314624011210
Lubabalo Ndima, Eric Cyriel Hosten, Richard Betz
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引用次数: 0

Abstract

The solvated title compound, (C18H16P)[CoCl3(C18H15P)]·2C6H6, is the tri-phenyl-phospho-nium salt of an anionic CoII chlorido coordination compound; the asymmetric unit features an ion-pair and two benzene solvent molecules. One of the solvent mol-ecules shows rotational disorder. C-H⋯Cl and P-H⋯Cl contacts connect the individual constituents into infinite chains extending parallel to [010].

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溶解的标题化合物 (C18H16P)[CoCl3(C18H15P)]-2C6H6,是阴离子 CoII 氯配位化合物的三苯基磷鎓盐,其不对称单元具有一个离子对和两个苯溶剂分子。其中一个溶剂分子显示出旋转紊乱。C-H⋯Cl 和 P-H⋯Cl 触点将各个成分连接成平行于 [010] 延伸的无限链。
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