Lubabalo Ndima , Eric Cyriel Hosten , Richard Betz
{"title":"Triphenylphosphonium trichlorido(triphenylphosphane-κP)cobaltate(II) benzene disolvate","authors":"Lubabalo Ndima , Eric Cyriel Hosten , Richard Betz","doi":"10.1107/S2414314624011210","DOIUrl":null,"url":null,"abstract":"<div><div>The central atom of the complex anion is coordinated by one triphenylphosphane and three chlorido ligands. The negative charge is balanced by a triphenylphosphonium cation. Two benzene solvent molecules are also present in the asymmetric unit.</div></div><div><div>The solvated title compound, (C<sub>18</sub>H<sub>16</sub>P)[CoCl<sub>3</sub>(C<sub>18</sub>H<sub>15</sub>P)]·2C<sub>6</sub>H<sub>6</sub>, is the triphenylphosphonium salt of an anionic Co<sup>II</sup> chlorido coordination compound; the asymmetric unit features an ion-pair and two benzene solvent molecules. One of the solvent molecules shows rotational disorder. C—H⋯Cl and P—H⋯Cl contacts connect the individual constituents into infinite chains extending parallel to [010].<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (406KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 11","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11618865/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S241431462400107X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
The central atom of the complex anion is coordinated by one triphenylphosphane and three chlorido ligands. The negative charge is balanced by a triphenylphosphonium cation. Two benzene solvent molecules are also present in the asymmetric unit.
The solvated title compound, (C18H16P)[CoCl3(C18H15P)]·2C6H6, is the triphenylphosphonium salt of an anionic CoII chlorido coordination compound; the asymmetric unit features an ion-pair and two benzene solvent molecules. One of the solvent molecules shows rotational disorder. C—H⋯Cl and P—H⋯Cl contacts connect the individual constituents into infinite chains extending parallel to [010].
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