The carbonate exchange reaction strategy for chemical recycling of poly(bisphenol A carbonate) into an epoxy-curing agent†

IF 3.9 2区 化学 Q2 POLYMER SCIENCE Polymer Chemistry Pub Date : 2024-12-04 Epub Date: 2024-12-10 DOI:10.1039/d4py01175a
Zengping Peng , Haoyue Chen , Maoqing Chai , Rulin Yang , Guangqiang Xu , Hongguang Sun , Qinggang Wang
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Abstract

Using chemical methods to depolymerize or convert plastic materials for recycling is a useful process to achieve a sustainable and circular plastic economy. Herein, different from conventional chemical methodologies to convert waste plastics into monomers or high value-added chemicals, a “waste polymer to precursor of polymer to new polymer” protocol was proposed. For the chemical recycling of poly(bisphenol A carbonate) (BPA-PC), a novel carbonate exchange strategy was explored, in which BPA-PC was depolymerized into “DPC-PC” via a diphenyl carbonate (DPC)-mediated carbonate exchange reaction. The unique structure of DPC-PC enables it to serve as a curing agent for preparing high-performance and recyclable epoxy thermosets, thus blazing a new trail for the chemical recycling of BPA-PC.

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将聚双酚 A 碳酸酯转化为环氧固化剂的化学循环利用碳酸酯交换反应策略
利用化学方法解聚或转化塑料材料进行循环利用是实现可持续和循环塑料经济的有效途径。与传统化学方法将废塑料转化为单体或高附加值化学品不同,提出了“废聚合物→聚合物前驱体→新聚合物”的方案。针对聚双酚A碳酸酯(BPA-PC)的化学回收,探索了一种新的碳酸酯交换策略,通过碳酸二苯酯(DPC)介导的碳酸酯交换反应将BPA-PC解聚为“DPC- pc”。独特的结构使DPC-PC成为制备高性能可回收环氧热固性树脂的固化剂,为BPA-PC的化学回收开辟了新的道路。
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来源期刊
Polymer Chemistry
Polymer Chemistry POLYMER SCIENCE-
CiteScore
8.60
自引率
8.70%
发文量
535
审稿时长
1.7 months
期刊介绍: Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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