Jorid Smets, Víctor Rubio-Giménez, Jesús Gándara-Loe, Jonas Adriaenssens, Mario Fratschko, Fabian Gasser, Roland Resel, Anita Brady-Boyd, Rajeshreddy Ninakanti, Steven De Feyter, Silvia Armini, Rob Ameloot
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引用次数: 0
Abstract
Integrating metal–organic frameworks (MOFs) into microfabrication processes will benefit from controlled vapor-phase deposition techniques. This study presents a molecular layer deposition method that enables area-selective and oriented growth of zeolitic imidazolate framework-8 (ZIF-8) films. Substrates functionalized with self-assembled monolayers (SAMs) with different end groups (alkyl, phenyl, hydroxyl, carboxyl, amine, and imidazole) allow tuning the degree of crystallographic orientation in the resulting MOF layers. Spatial control over SAM formation determined the surface mobility of the ZIF-8 building blocks, which enabled area-selective deposition.
期刊介绍：
The journal Chemistry of Materials focuses on publishing original research at the intersection of materials science and chemistry. The studies published in the journal involve chemistry as a prominent component and explore topics such as the design, synthesis, characterization, processing, understanding, and application of functional or potentially functional materials. The journal covers various areas of interest, including inorganic and organic solid-state chemistry, nanomaterials, biomaterials, thin films and polymers, and composite/hybrid materials. The journal particularly seeks papers that highlight the creation or development of innovative materials with novel optical, electrical, magnetic, catalytic, or mechanical properties. It is essential that manuscripts on these topics have a primary focus on the chemistry of materials and represent a significant advancement compared to prior research. Before external reviews are sought, submitted manuscripts undergo a review process by a minimum of two editors to ensure their appropriateness for the journal and the presence of sufficient evidence of a significant advance that will be of broad interest to the materials chemistry community.
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