{"title":"Dearomative 2,3-diamination of indoles triggered by Rh(iii)-catalyzed Csp2–H activation†","authors":"Chengjie Wang , Huanfeng Jiang , Wei Zeng","doi":"10.1039/d4qo02017k","DOIUrl":null,"url":null,"abstract":"<div><div>An Rh(<span>iii</span>)-catalyzed dearomative 2,3-diamination of indoles with <em>N</em>-alkoxyamides has been developed. The method provides an efficient approach to access 2-(<em>N</em>-acylimino)-3-aminoindolines with high regioselectivity.</div></div>","PeriodicalId":94379,"journal":{"name":"Organic chemistry frontiers : an international journal of organic chemistry","volume":"12 6","pages":"Pages 1821-1826"},"PeriodicalIF":0.0000,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic chemistry frontiers : an international journal of organic chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2052412925000385","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
An Rh(iii)-catalyzed dearomative 2,3-diamination of indoles with N-alkoxyamides has been developed. The method provides an efficient approach to access 2-(N-acylimino)-3-aminoindolines with high regioselectivity.
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