Growth of MoS2 Nanosheets on Brush-Shaped PI-ZnO Hybrid Nanofibers and Study of the Photocatalytic Performance.

Abstract

The design and preparation of advanced hybrid nanofibers with controllable microstructures will be interesting because of their potential high-efficiency applications in the environmental and energy domains. In this paper, a simple and efficient strategy was developed for preparing hybrid nanofibers of zinc oxide-molybdenum disulfide (ZnO-MoS₂) grown on polyimide (PI) nanofibers by combining electrospinning, a high-pressure hydrothermal process, and in situ growth. Unlike simple composite nanoparticles, the structure is shown in PI-ZnO to be like the skeleton of a tree for the growth of MoS₂ "leaves" as macro-materials with controlled microstructures. The surface morphology, structure, composition, and photocatalytic properties of these structures were characterized using scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and UV-vis spectroscopy. The ultra high-volume fraction of MoS₂ can be grown on the brush-shaped PI-ZnO. Decorating ZnO with nanosheets of MoS₂ (a transition metal dichalcogenide with a relatively narrow band gap) is a promising way to increase the photocatalytic activity of ZnO. The hybrid nanofibers exhibited high photocatalytic properties, which decomposed about 92% of the methylene blue in 90 min under visible light irradiation. The combination of MoS₂ and ZnO with more abundant surface-active sites significantly increases the spectral absorption range, promotes the separation and migration of carriers, and improves the photocatalytic characteristics.