Laser-Induced Emission Spectra of La0.95Nd0.05MnO3 Nanocrystals

IF 3.2 3区 化学 Q2 CHEMISTRY, PHYSICAL The Journal of Physical Chemistry C Pub Date : 2025-01-15 DOI:10.1021/acs.jpcc.4c07266
João M. Gonçalves, Mariusz Stefanski, Robert Tomala, Agata Musialek, Bartłomiej Cichy, Marco Bettinelli, Wieslaw Strek
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Abstract

The luminescence spectral properties of La0.95Nd0.05MnO3 were investigated upon irradiation with a focused 808 nm CW (continuous wave) laser excitation. An anti-Stokes broadband emission in the visible range centered at 670 nm and a Stokes band in the infrared range centered around 2000 nm were recorded. Their intensities increased exponentially with excitation laser power. The mechanism of laser-induced emission is discussed in terms of an intervalence charge transfer mechanism involving the Mn3+–Mn4+ ionic pair.

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La0.95Nd0.05MnO3纳米晶体的激光诱导发射光谱
研究了 La0.95Nd0.05MnO3 在聚焦 808 nm CW(连续波)激光激发下的发光光谱特性。在可见光范围内记录到以 670 纳米为中心的反斯托克斯宽带发射,在红外线范围内记录到以 2000 纳米为中心的斯托克斯带。它们的强度随激发激光功率的增加而呈指数增长。本文从涉及 Mn3+-Mn4+ 离子对的间隔电荷转移机制的角度讨论了激光诱导发射的机理。
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来源期刊
The Journal of Physical Chemistry C
The Journal of Physical Chemistry C 化学-材料科学:综合
CiteScore
6.50
自引率
8.10%
发文量
2047
审稿时长
1.8 months
期刊介绍: The Journal of Physical Chemistry A/B/C is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, and chemical physicists.
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