Experimental Simulation of Pyrolysis Products Recycling via Detonation

IF 1.4 4区 化学 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL Russian Journal of Physical Chemistry B Pub Date : 2025-01-15 DOI:10.1134/S1990793124701379
E. K. Anderzhanov, S. P. Medvedev, S. V. Khomik, G. L. Agafonov, A. N. Ivantsov, V. N. Mikhalkin, A. M. Tereza, I. V. Bilera
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Abstract

Earlier the efficiency of a stand in form of the open-end Π-shape tube for deflagration-to-detonation transition (DDT) of propane—air mixtures at normal pressure was shown. In this work, the study of the DDT is extended to the mixtures modeling real gaseous pyrolysis products of polyethylene and rubber-containing industrial and domestic waste. Modeling mixtures with air contain Н2, СН4, С2Н6, С2Н4, С3Н8 and С3Н6 in stoichiometric or lean concentration based on the experimental data presented in the literature. Conditions when the DDT can be reached (stand design, initial pyrolysis products mixture concentration) are defined. Measurements of the temperature of the mixture passed through the stand in addition to dynamic measurements allow to define the character of the processing: DDT, fast or slow deflagration. It has been shown that propane as a model fuel may be used instead of pyrolysis gases mixtures when studying DDT. The results supposed to be helpful for the waste recycling industrial setups engineering.

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热解产物爆轰回收的实验模拟
早些时候,展示了常压下丙烷-空气混合物爆燃-爆轰过渡(DDT)的开放式Π-shape管形式的支架的效率。在这项工作中,DDT的研究扩展到模拟聚乙烯和含橡胶的工业和生活废物的真实气体热解产物的混合物。根据文献中提供的实验数据,模拟空气混合物中含有Н2, СН4, С2Н6, С2Н4, С3Н8和С3Н6的化学计量或贫浓度。确定了达到DDT的条件(台架设计、初始热解产物混合物浓度)。除了动态测量外,通过机架的混合物温度测量允许定义处理的特性:滴滴涕,快速或缓慢爆燃。研究表明,在研究DDT时,可以用丙烷代替热解气体混合物作为模型燃料。研究结果对垃圾回收工业装置工程具有一定的指导意义。
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来源期刊
Russian Journal of Physical Chemistry B
Russian Journal of Physical Chemistry B 化学-物理:原子、分子和化学物理
CiteScore
2.20
自引率
71.40%
发文量
106
审稿时长
4-8 weeks
期刊介绍: Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.
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