Mustapha El Kadiri , Abdelhaq Cherradi , Oleg A. Filippov , Carine Duhayon , Vincent César , Elena S. Shubina , Mohammed Lahcini , Dmitry A. Valyaev , Yves Canac
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引用次数: 0
Abstract
The grafting of a –(CH2)2PR3+ moiety on an NHC ligand backbone in the Mn(i) complex [Cp(CO)2Mn(IMes)] followed by double deprotonation opens a route to bidentate ligands with extreme electron-donating character. Such remarkable electronic properties can even allow intramolecular sp2 C–H functionalization in typically inert square-planar Rh(i) dicarbonyl complexes.
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