Tandem construction of flavone-bridged conjugated porous polymers for photosynthesis of 2,3-dihydrobenzofurans†

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2025-01-24 Epub Date: 2025-01-23 DOI:10.1039/d4cc06631f
Kuan Chen , Hailong Shen , Yansong Hu , Jiyu Liu , Kaixuan Guo , Zengxiang Wang , Qing Huang , Yuan Zhang
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Abstract

Conjugated porous polymers bearing flavone moieties (FL-CPPs) were synthesized via a tandem approach. The carbonylative Sonogashira coupling in tandem with cyclization guided the assembling of building blocks with the accompanied production of flavone skeletons. The FL-CPPs were proved to be efficient metal-free photocatalysts for the [3+2] cycloaddition of phenols with olefins under the irradiation of visible-light.

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用于2,3-二氢苯并呋喃光合作用的黄酮桥联共轭多孔聚合物的串联构建
采用串联法合成了含黄酮基团的共轭多孔聚合物。羰基化Sonogashira偶联与环化串联引导构建块的组装与伴随的黄酮骨架的生产。结果表明,在可见光照射下,FL-CPPs是苯酚与烯烃[3+2]环加成反应的高效无金属光催化剂。
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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