Kuan Chen , Hailong Shen , Yansong Hu , Jiyu Liu , Kaixuan Guo , Zengxiang Wang , Qing Huang , Yuan Zhang
{"title":"Tandem construction of flavone-bridged conjugated porous polymers for photosynthesis of 2,3-dihydrobenzofurans†","authors":"Kuan Chen , Hailong Shen , Yansong Hu , Jiyu Liu , Kaixuan Guo , Zengxiang Wang , Qing Huang , Yuan Zhang","doi":"10.1039/d4cc06631f","DOIUrl":null,"url":null,"abstract":"<div><div>Conjugated porous polymers bearing flavone moieties (FL-CPPs) were synthesized <em>via</em> a tandem approach. The carbonylative Sonogashira coupling in tandem with cyclization guided the assembling of building blocks with the accompanied production of flavone skeletons. The FL-CPPs were proved to be efficient metal-free photocatalysts for the [3+2] cycloaddition of phenols with olefins under the irradiation of visible-light.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"61 15","pages":"Pages 3171-3174"},"PeriodicalIF":4.2000,"publicationDate":"2025-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734525001430","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/1/23 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Conjugated porous polymers bearing flavone moieties (FL-CPPs) were synthesized via a tandem approach. The carbonylative Sonogashira coupling in tandem with cyclization guided the assembling of building blocks with the accompanied production of flavone skeletons. The FL-CPPs were proved to be efficient metal-free photocatalysts for the [3+2] cycloaddition of phenols with olefins under the irradiation of visible-light.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.