One-step synthesis of N-coordinated Rh catalysts for efficient and stable alkene hydroformylation†

IF 4.2 3区 化学 Q2 CHEMISTRY, PHYSICAL Catalysis Science & Technology Pub Date : 2024-12-16 Epub Date: 2025-01-15 DOI:10.1039/d4cy01146e
Yongcheng Lan , Jia Wang , Dong Yun , Chungu Xia , Bo Qian , Jianhua Liu
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Abstract

A new class of nitrogen-coordinated Rh heterogeneous catalyst was synthesized by a simple one-pot method for hydroformylation of alkenes with high activity and superior resuability, which could be ascribed to the uniform dispersion of Rh species and enhanced metal–support interactions after the in situ introduction of nitrogen.

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一步法合成高效稳定的烯烃氢甲酰化n -配位Rh催化剂
采用简单的一锅法合成了一类新的氮配位Rh非均相催化剂,用于烯烃的氢甲酰化反应,具有较高的活性和较好的可再生性,这可归因于原位引入氮后Rh物种的均匀分散和金属-负载相互作用的增强。
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来源期刊
Catalysis Science & Technology
Catalysis Science & Technology CHEMISTRY, PHYSICAL-
CiteScore
8.70
自引率
6.00%
发文量
587
审稿时长
1.5 months
期刊介绍: A multidisciplinary journal focusing on cutting edge research across all fundamental science and technological aspects of catalysis. Editor-in-chief: Bert Weckhuysen Impact factor: 5.0 Time to first decision (peer reviewed only): 31 days
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