Oliver A. Müller, Marcel J. P. Schmitt, Christoph Riehn, Sabine Becker
{"title":"Front Cover: A Reversibly Photoswitchable Zinc Metallocycle based on Azobenzene (Eur. J. Inorg. Chem. 2/2025)","authors":"Oliver A. Müller, Marcel J. P. Schmitt, Christoph Riehn, Sabine Becker","doi":"10.1002/ejic.202580201","DOIUrl":null,"url":null,"abstract":"<p><b>The Front Cover</b> highlights the novel azobenzene-based ligand 3,3’-azobenz(BPA)<sub>2</sub> (<b>1</b>). Upon reaction with Zn(BF<sub>4</sub>)<sub>2</sub> and ZnCl<sub>2</sub>, the metallocycle [Zn<sub>2</sub>(<b>1</b>)<sub>2</sub>)](BF<sub>4</sub>)<sub>4</sub> and the linear complex [{ZnCl<sub>2</sub>}<sub>2</sub>(<b>1</b>)] are formed (shown left and right). Both complexes retain the reversible photoswitchability of the ligand and do not disassemble during photoisomerization. Reversible photoisomerization was observed with NMR and UV/Vis spectroscopy, which spectra are shown schematically in the background. More information can be found in the Research Article by S. Becker and co-workers.\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 2","pages":""},"PeriodicalIF":2.0000,"publicationDate":"2025-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202580201","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Inorganic Chemistry","FirstCategoryId":"1","ListUrlMain":"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202580201","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The Front Cover highlights the novel azobenzene-based ligand 3,3’-azobenz(BPA)2 (1). Upon reaction with Zn(BF4)2 and ZnCl2, the metallocycle [Zn2(1)2)](BF4)4 and the linear complex [{ZnCl2}2(1)] are formed (shown left and right). Both complexes retain the reversible photoswitchability of the ligand and do not disassemble during photoisomerization. Reversible photoisomerization was observed with NMR and UV/Vis spectroscopy, which spectra are shown schematically in the background. More information can be found in the Research Article by S. Becker and co-workers.
期刊介绍：
The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry:
Chemische Berichte
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry
The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
