A novel and green approach for the synthesis of copper nanoparticles and their applications in reduction of nitroarenes and degradation of organic dyes

IF 2.1 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Journal of Organometallic Chemistry Pub Date : 2025-02-01 Epub Date: 2024-12-15 DOI:10.1016/j.jorganchem.2024.123477
Babak Kaboudin , Bahman Burunli , Mahdi Nazerian , Tianjian Zhang , Yanlong Gu
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Abstract

Copper nanoparticles (Cu-NPs) were synthesized using a complex of copper with β-cyclodextrin (Cu2-β-CD) by the hydrothermal method in an aqueous solution. The synthesis proceeded without adding any additives such as reducing agents. The structural characterization of copper nanoparticles has been carried out by scanning electron microscopy (SEM) images, EDS, XRD, and TGA analysis. Application of the catalytic activity of the obtained Cu-NPs was performed for the reduction of nitroaromatic compounds. A catalytic degradation of Methylene Blue and Methyl Orange solutions in the presence of Cu-NPs was also studied in order to examine the nanoparticles influence on degradation.

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一种新的绿色合成纳米铜的方法及其在硝基芳烃还原和有机染料降解中的应用
以铜与β-环糊精(Cu2-β-CD)配合物为原料,在水溶液中采用水热法制备了铜纳米粒子(Cu-NPs)。合成过程中没有添加还原剂等任何添加剂。通过扫描电镜(SEM)、能谱仪(EDS)、x射线衍射(XRD)和热重分析(TGA)对铜纳米颗粒进行了结构表征。将所得Cu-NPs的催化活性应用于硝基芳香族化合物的还原。为了考察纳米颗粒对降解的影响,还研究了Cu-NPs存在下亚甲基蓝和甲基橙溶液的催化降解。
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来源期刊
Journal of Organometallic Chemistry
Journal of Organometallic Chemistry 化学-无机化学与核化学
CiteScore
4.40
自引率
8.70%
发文量
221
审稿时长
36 days
期刊介绍: The Journal of Organometallic Chemistry targets original papers dealing with theoretical aspects, structural chemistry, synthesis, physical and chemical properties (including reaction mechanisms), and practical applications of organometallic compounds. Organometallic compounds are defined as compounds that contain metal - carbon bonds. The term metal includes all alkali and alkaline earth metals, all transition metals and the lanthanides and actinides in the Periodic Table. Metalloids including the elements in Group 13 and the heavier members of the Groups 14 - 16 are also included. The term chemistry includes syntheses, characterizations and reaction chemistry of all such compounds. Research reports based on use of organometallic complexes in bioorganometallic chemistry, medicine, material sciences, homogeneous catalysis and energy conversion are also welcome. The scope of the journal has been enlarged to encompass important research on organometallic complexes in bioorganometallic chemistry and material sciences, and of heavier main group elements in organometallic chemistry. The journal also publishes review articles, short communications and notes.
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