The chemistry of bimetallic surfaces – Evolution of an atomic-scale picture

IF 1.8 4区 化学 Q3 CHEMISTRY, PHYSICAL Surface Science Pub Date : 2024-12-03 DOI:10.1016/j.susc.2024.122677
R. Jürgen Behm, Axel Groß
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Abstract

In this contribution, we will review the concepts and principles used to characterize and discuss the structure, stability, adsorption properties and catalytic reactivity of bimetallic surfaces in an atomic-scale picture. Starting from early stages, we will emphasize recent experimental and theoretical findings that resulted in a rapidly improving atomic-scale understanding of adsorption and catalytic surface reactions on these surfaces. While examples are often taken from our own work, the resulting insights are of general validity.

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双金属表面的化学性质——原子尺度图像的演化
在这篇文章中,我们将回顾用于表征和讨论双金属表面在原子尺度上的结构、稳定性、吸附性能和催化反应性的概念和原理。从早期阶段开始,我们将强调最近的实验和理论发现,这些发现导致了对这些表面上的吸附和催化表面反应的原子尺度理解的迅速提高。虽然例子通常取自我们自己的工作,但由此得出的见解具有普遍的有效性。
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来源期刊
Surface Science
Surface Science 化学-物理:凝聚态物理
CiteScore
3.30
自引率
5.30%
发文量
137
审稿时长
25 days
期刊介绍: Surface Science is devoted to elucidating the fundamental aspects of chemistry and physics occurring at a wide range of surfaces and interfaces and to disseminating this knowledge fast. The journal welcomes a broad spectrum of topics, including but not limited to: • model systems (e.g. in Ultra High Vacuum) under well-controlled reactive conditions • nanoscale science and engineering, including manipulation of matter at the atomic/molecular scale and assembly phenomena • reactivity of surfaces as related to various applied areas including heterogeneous catalysis, chemistry at electrified interfaces, and semiconductors functionalization • phenomena at interfaces relevant to energy storage and conversion, and fuels production and utilization • surface reactivity for environmental protection and pollution remediation • interactions at surfaces of soft matter, including polymers and biomaterials. Both experimental and theoretical work, including modeling, is within the scope of the journal. Work published in Surface Science reaches a wide readership, from chemistry and physics to biology and materials science and engineering, providing an excellent forum for cross-fertilization of ideas and broad dissemination of scientific discoveries.
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