Heavy metals removal from mine wastewater using polysulfone membrane infused with waste plastic-derived carbon nanotubes as filler

H.U. Modekwe , I.M. Ramatsa , M.A. Mamo , O.O. Sadare , M.O. Daramola , K. Moothi
{"title":"Heavy metals removal from mine wastewater using polysulfone membrane infused with waste plastic-derived carbon nanotubes as filler","authors":"H.U. Modekwe ,&nbsp;I.M. Ramatsa ,&nbsp;M.A. Mamo ,&nbsp;O.O. Sadare ,&nbsp;M.O. Daramola ,&nbsp;K. Moothi","doi":"10.1016/j.wmb.2024.12.005","DOIUrl":null,"url":null,"abstract":"<div><div>The study focuses on “treating waste with waste” through the removal of toxic metals from gold mine wastewater using polysulfone (PSF) membrane infused with waste plastic derived-multi-walled carbon nanotube (MWCNTs) as an innovative approach. MWCNTs synthesized from waste polypropylene (PP) plastics by the chemical vapour deposition (CVD) method were purified in oxidizing acid, and different loadings (0, 0.05, 0.10, and 0.15 wt%) were incorporated into the PSF membrane to form mixed matrix membranes (MMM) via phase inversion technique. Fabricated pristine and nanocomposite membranes’ properties: hydrophilicity, thermal stability, and morphology, were ascertained by the water contact angle measurement, thermogravimetry analysis, and scanning electron microscopy, respectively. Results show that incorporating plastic-derived-MWCNTs into the matrices of PSF polymer significantly enhanced the properties of all fabricated MWCNTs/PSF nanocomposite membranes compared to pristine PSF. The flux and rejection of metals increased with MWCNTs loading. Iron (Fe) and nickel (Ni) removal by pristine PSF were 70.2% and 11.4%, respectively, while optimal Fe and Ni rejection of 91% and 74%, respectively, were obtained with 0.10 wt% MWCNT loading. The results obtained in this work revealed that incorporating different loadings of plastic-derived-MWCNTs onto the PSF polymer matrix impacted its surface properties, and improved flux, and removal efficiency. Therefore, utilizing waste plastics as a precursor in CNTs production will save on the cost of CNTs and provide a sustainable plastic waste management option, as well as open up vast prospects at the industrial scale in the potential for application in environmental remediation (such as in membrane separation).</div></div>","PeriodicalId":101276,"journal":{"name":"Waste Management Bulletin","volume":"3 1","pages":"Pages 39-47"},"PeriodicalIF":0.0000,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Waste Management Bulletin","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S294975072400107X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

Abstract

The study focuses on “treating waste with waste” through the removal of toxic metals from gold mine wastewater using polysulfone (PSF) membrane infused with waste plastic derived-multi-walled carbon nanotube (MWCNTs) as an innovative approach. MWCNTs synthesized from waste polypropylene (PP) plastics by the chemical vapour deposition (CVD) method were purified in oxidizing acid, and different loadings (0, 0.05, 0.10, and 0.15 wt%) were incorporated into the PSF membrane to form mixed matrix membranes (MMM) via phase inversion technique. Fabricated pristine and nanocomposite membranes’ properties: hydrophilicity, thermal stability, and morphology, were ascertained by the water contact angle measurement, thermogravimetry analysis, and scanning electron microscopy, respectively. Results show that incorporating plastic-derived-MWCNTs into the matrices of PSF polymer significantly enhanced the properties of all fabricated MWCNTs/PSF nanocomposite membranes compared to pristine PSF. The flux and rejection of metals increased with MWCNTs loading. Iron (Fe) and nickel (Ni) removal by pristine PSF were 70.2% and 11.4%, respectively, while optimal Fe and Ni rejection of 91% and 74%, respectively, were obtained with 0.10 wt% MWCNT loading. The results obtained in this work revealed that incorporating different loadings of plastic-derived-MWCNTs onto the PSF polymer matrix impacted its surface properties, and improved flux, and removal efficiency. Therefore, utilizing waste plastics as a precursor in CNTs production will save on the cost of CNTs and provide a sustainable plastic waste management option, as well as open up vast prospects at the industrial scale in the potential for application in environmental remediation (such as in membrane separation).
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
求助全文
约1分钟内获得全文 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Rapid on-site maturity and stability assessment of sewage sludge compost by mathematical treatment of UV and fluorescence spectroscopic data Profiling PBDE emissions from coastal landfills: Impact of waste management practices Sustainable recovery of rare Earth elements from industrial waste: A path to circular economy and environmental health Two inorganic materials were prepared by calcination-acid leaching combined treatment of coal gangue: Al&Fe enriched acid solution and Si enriched material A novel Hausdorff fractional grey Bernoulli model and its Application in forecasting electronic waste
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1