Established electrochemistry theory rules out the existence of exclusion-zone water at polarized Pt electrodes

IF 3.1 3区 化学 Q3 CHEMISTRY, PHYSICAL Chemical Physics Letters Pub Date : 2025-04-16 Epub Date: 2025-01-30 DOI:10.1016/j.cplett.2025.141920
Fabrizio Sordello
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Abstract

Exclusion-zone water has been proposed to explain anomalous behavior of water compared with other liquids, like exceptionally large capacitance measured at polarized Pt electrodes. Conventional electrochemistry theory can account for the experimental data without introducing a novel water phase stable at room temperature.

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现有的电化学理论排除了极化Pt电极上排斥带水的存在
排斥带水被用来解释水与其他液体相比的异常行为,比如在极化Pt电极上测量的异常大的电容。传统的电化学理论可以解释实验数据,而不需要引入新的室温稳定的水相。
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来源期刊
Chemical Physics Letters
Chemical Physics Letters 化学-物理:原子、分子和化学物理
CiteScore
5.70
自引率
3.60%
发文量
798
审稿时长
33 days
期刊介绍: Chemical Physics Letters has an open access mirror journal, Chemical Physics Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. Chemical Physics Letters publishes brief reports on molecules, interfaces, condensed phases, nanomaterials and nanostructures, polymers, biomolecular systems, and energy conversion and storage. Criteria for publication are quality, urgency and impact. Further, experimental results reported in the journal have direct relevance for theory, and theoretical developments or non-routine computations relate directly to experiment. Manuscripts must satisfy these criteria and should not be minor extensions of previous work.
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