Crystal structure and Hirshfeld surface analysis of the organic-inorganic hybrid compound tris-(2-iodo-ethyl-ammonium) hexa-iodido-bis-muthate(III).

IF 0.5 Q4 CRYSTALLOGRAPHY Acta Crystallographica Section E: Crystallographic Communications Pub Date : 2025-01-24 eCollection Date: 2025-02-01 DOI:10.1107/S2056989025000386
Olesia I Kucheriv, Valeriia M Ovdenko, Iryna S Kuzevanova, Irina A Golenya, Il'ya A Gural'skiy
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引用次数: 0

Abstract

The asymmetric unit of the title organic-inorganic salt, (IC2H4NH3)3[BiI6], consists of a [BiI6]3- octa-hedron and three 2-iodo-ethyl-ammonium cations. The octa-hedra do not inter-act with each other, and the supra-molecular arrangement is ensured by an intricate network of N-H⋯I hydrogen bonds between cations and anions. In addition, a weak I⋯I inter-action between an organic cation and the coordination octa-hedron is present in the crystal structure. Hirshfeld surface analysis revealed that the most important contributions to the crystal packing are from H⋯I (72.3%) and I⋯I (11.3%) inter-actions.

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来源期刊
CiteScore
1.90
自引率
0.00%
发文量
351
审稿时长
3 weeks
期刊介绍: Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.
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