Olesia I Kucheriv, Valeriia M Ovdenko, Iryna S Kuzevanova, Irina A Golenya, Il'ya A Gural'skiy
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引用次数: 0
Abstract
The asymmetric unit of the title organic-inorganic salt, (IC2H4NH3)3[BiI6], consists of a [BiI6]3- octa-hedron and three 2-iodo-ethyl-ammonium cations. The octa-hedra do not inter-act with each other, and the supra-molecular arrangement is ensured by an intricate network of N-H⋯I hydrogen bonds between cations and anions. In addition, a weak I⋯I inter-action between an organic cation and the coordination octa-hedron is present in the crystal structure. Hirshfeld surface analysis revealed that the most important contributions to the crystal packing are from H⋯I (72.3%) and I⋯I (11.3%) inter-actions.
期刊介绍:
Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.