Small organic fluorophores with SWIR emission detectable beyond 1300 nm†

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2025-03-03 Epub Date: 2025-02-18 DOI:10.1039/d4cc05248j
Michal Pieczykolan , Pierre Alix Dancer , Tjadina-Wencke Klein , Hubert Piwonski , Hannes Rolbieski , Bholanath Maity , Oliver T. Bruns , Luigi Cavallo , Fabian Kiessling , Magnus Rueping , Srinivas Banala
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Abstract

3,6-Dimethylamino fluorenone was functionalized with substituents to achieve an absorption maximum at 1012 nm and emission >1300 nm. TD-DFT calculations confirmed that the substituent orbitals contribute to narrowing the HOMO–LUMO energy gap. Imaging with an InGaAs-based SWIR camera and various longpass filters confirmed detection >1300 nm.

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小有机荧光团与SWIR发射可检测超过1300nm
通过取代基对 3,6-二甲基氨基芴酮进行官能化,使其在 1012 纳米波长处达到吸收最大值,并在 1300 纳米波长处发射。TD-DFT 计算证实,取代基轨道有助于缩小 HOMO-LUMO 能量。使用基于 InGaAs 的 SWIR 相机和各种长通滤光片进行的成像证实,探测波长为 1300 nm。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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