Michal Pieczykolan , Pierre Alix Dancer , Tjadina-Wencke Klein , Hubert Piwonski , Hannes Rolbieski , Bholanath Maity , Oliver T. Bruns , Luigi Cavallo , Fabian Kiessling , Magnus Rueping , Srinivas Banala
{"title":"Small organic fluorophores with SWIR emission detectable beyond 1300 nm†","authors":"Michal Pieczykolan , Pierre Alix Dancer , Tjadina-Wencke Klein , Hubert Piwonski , Hannes Rolbieski , Bholanath Maity , Oliver T. Bruns , Luigi Cavallo , Fabian Kiessling , Magnus Rueping , Srinivas Banala","doi":"10.1039/d4cc05248j","DOIUrl":null,"url":null,"abstract":"<div><div>3,6-Dimethylamino fluorenone was functionalized with substituents to achieve an absorption maximum at 1012 nm and emission >1300 nm. TD-DFT calculations confirmed that the substituent orbitals contribute to narrowing the HOMO–LUMO energy gap. Imaging with an InGaAs-based SWIR camera and various longpass filters confirmed detection >1300 nm.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"61 25","pages":"Pages 4820-4823"},"PeriodicalIF":4.2000,"publicationDate":"2025-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/cc/d4cc05248j?page=search","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734525004008","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/2/18 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
3,6-Dimethylamino fluorenone was functionalized with substituents to achieve an absorption maximum at 1012 nm and emission >1300 nm. TD-DFT calculations confirmed that the substituent orbitals contribute to narrowing the HOMO–LUMO energy gap. Imaging with an InGaAs-based SWIR camera and various longpass filters confirmed detection >1300 nm.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.