XPS and TEM characterization of oxides formed in simulated primary water on steam generator tubes made of Ni based alloy

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-06-01 Epub Date: 2025-02-25 DOI:10.1016/j.corsci.2025.112823
Nathan Ribière , Jérôme Esvan , Nathalie Engler , Daniel Brimbal , Milan Skocic , Éric Andrieu , Christine Blanc , Lydia Laffont
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Abstract

Corrosion of Ni-based alloy steam generator tubes in simulated primary water leads to the formation of oxides on the surface of the tubes and to the release of corrosion products. The oxides formed on two industrial samples were studied using X-ray photoemission spectroscopy and transmission electron microscopy. The morphology, structure and composition of the oxide layers were determined, and the differences observed were discussed in relation to previous analyses on the as-received inner surfaces. A fine grains layer, alumina on the surface of native oxides could influence the behavior of the surface in primary water.
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镍基合金蒸汽发生器管模拟一次水中氧化物的XPS和TEM表征
镍基合金蒸汽发生器管在模拟一次水中的腐蚀导致管表面形成氧化物并释放腐蚀产物。用x射线光发射光谱和透射电子显微镜研究了两个工业样品上形成的氧化物。测定了氧化层的形貌、结构和组成,并讨论了观察到的差异与先前对接收内表面的分析有关。天然氧化物表面的细小晶粒层氧化铝会影响原生水中表面的行为。
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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