Zhi-Wei Li , Anlian Huang , Zhenguo Wang , Rui Gao , Bang Lan , Guosheng Chen , Gangfeng Ouyang
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引用次数: 0
Abstract
We report a solvent-mediated subcomponent self-assembly strategy for synthesizing tetranuclear and triangular covalent metallacycles. The results demonstrate that the polarity of solvent significantly influences the structural outcome of metallacycles, and the square-shaped metallacycles can serve as building blocks for the construction of hierarchical porous materials such as metallacycle-based hydrogen-bonded organic frameworks (mHOFs) and metal–organic frameworks (mMOFs).
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