{"title":"Solvent-mediated subcomponent self-assembly of covalent metallacycles for hierarchical porous materials synthesis","authors":"Zhi-Wei Li, Anlian Huang, Zhenguo Wang, Rui Gao, Bang Lan, Guosheng Chen, Gangfeng Ouyang","doi":"10.1039/d5cc00688k","DOIUrl":null,"url":null,"abstract":"We report a solvent-mediated subcomponent self-assembly strategy for synthesizing tetranuclear and triangular covalent metallacycles. The results demonstrate that the polarity of solvent significantly influences the structural outcome of metallacycles, and the square-shaped metallacycles can serve as building blocks for the construction of hierarchical porous materials such as metallacycle-based hydrogen-bonded organic frameworks (mHOFs) and metal-organic frameworks (mMOFs).","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"66 1","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2025-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5cc00688k","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
We report a solvent-mediated subcomponent self-assembly strategy for synthesizing tetranuclear and triangular covalent metallacycles. The results demonstrate that the polarity of solvent significantly influences the structural outcome of metallacycles, and the square-shaped metallacycles can serve as building blocks for the construction of hierarchical porous materials such as metallacycle-based hydrogen-bonded organic frameworks (mHOFs) and metal-organic frameworks (mMOFs).
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