Ralf Herbert Kern, Paul Leon Schmiedel, Hartmut Schubert, Lars Wesemann
{"title":"Heterocycles in reactions with boradigermaallyl","authors":"Ralf Herbert Kern, Paul Leon Schmiedel, Hartmut Schubert, Lars Wesemann","doi":"10.1039/d5cc00639b","DOIUrl":null,"url":null,"abstract":"Reactions of boradigermaallyl, which can also be regarded as a chloroborylene stabilzed by two germylene donors, with thiophene, furan, pyridazine and 2,2’-bipyridine are presented. Insertion of the boron atom into the heterocycles is observed and the resulting heterocycles continue to react with the bis(germylene) molecule.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"54 4 1","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2025-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5cc00639b","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
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Abstract
Reactions of boradigermaallyl, which can also be regarded as a chloroborylene stabilzed by two germylene donors, with thiophene, furan, pyridazine and 2,2’-bipyridine are presented. Insertion of the boron atom into the heterocycles is observed and the resulting heterocycles continue to react with the bis(germylene) molecule.
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