Hao-Yu Zhu , Suo Peng , Li-Jun Xue , Yi Zhang , Wei-Min Chen , Lu Xue , Fang-Ming Wang , Li-Li Wen
{"title":"Encapsulating Rhodamine 6G in a new anionic in-based metal-organic framework to realize pure white light emission","authors":"Hao-Yu Zhu , Suo Peng , Li-Jun Xue , Yi Zhang , Wei-Min Chen , Lu Xue , Fang-Ming Wang , Li-Li Wen","doi":"10.1016/j.ica.2025.122619","DOIUrl":null,"url":null,"abstract":"<div><div>Herein, we report a new blue emission metal-organic framework [(CH<sub>3</sub>)<sub>2</sub>NH<sub>2</sub><sup>+</sup>]In (C<sub>28</sub>H<sub>12</sub>N<sub>2</sub>O<sub>8</sub>) (MOF) (<strong>In-BCTC</strong>) with high porosity and internal quantum yield (IQY) at 6.97 % based on the ligand [9,9′-bicarbazole]-3,3′,6,6′-tetracarboxylic acid (H<sub>4</sub>BCTC) by solvothermal method. When encapsulating trace amounts (0.003 wt%) of an orange-emitting dye Rhodamine 6G (Rho6G), there obtains bright pure white light emitting material Rho6G@<strong>In-BCTC</strong> with an ideal CIE coordinate of (0.33, 0.33) and increases its IQY up to 23.65 %, with the moderate correlated color temperature (CCT: 5566 K). It is an interesting development in a MOF-based white-light-emitting phosphors.</div></div>","PeriodicalId":13599,"journal":{"name":"Inorganica Chimica Acta","volume":"581 ","pages":"Article 122619"},"PeriodicalIF":2.7000,"publicationDate":"2025-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganica Chimica Acta","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0020169325000854","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Herein, we report a new blue emission metal-organic framework [(CH3)2NH2+]In (C28H12N2O8) (MOF) (In-BCTC) with high porosity and internal quantum yield (IQY) at 6.97 % based on the ligand [9,9′-bicarbazole]-3,3′,6,6′-tetracarboxylic acid (H4BCTC) by solvothermal method. When encapsulating trace amounts (0.003 wt%) of an orange-emitting dye Rhodamine 6G (Rho6G), there obtains bright pure white light emitting material Rho6G@In-BCTC with an ideal CIE coordinate of (0.33, 0.33) and increases its IQY up to 23.65 %, with the moderate correlated color temperature (CCT: 5566 K). It is an interesting development in a MOF-based white-light-emitting phosphors.
期刊介绍：
Inorganica Chimica Acta is an established international forum for all aspects of advanced Inorganic Chemistry. Original papers of high scientific level and interest are published in the form of Articles and Reviews.
Topics covered include:
• chemistry of the main group elements and the d- and f-block metals, including the synthesis, characterization and reactivity of coordination, organometallic, biomimetic, supramolecular coordination compounds, including associated computational studies;
• synthesis, physico-chemical properties, applications of molecule-based nano-scaled clusters and nanomaterials designed using the principles of coordination chemistry, as well as coordination polymers (CPs), metal-organic frameworks (MOFs), metal-organic polyhedra (MPOs);
• reaction mechanisms and physico-chemical investigations computational studies of metalloenzymes and their models;
• applications of inorganic compounds, metallodrugs and molecule-based materials.
Papers composed primarily of structural reports will typically not be considered for publication.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
