Features of Trimetylolpropane Trimethacrylate Synthesis

IF 0.58 Q4 Materials Science Polymer Science, Series D Pub Date : 2025-03-16 DOI:10.1134/S1995421224701533
K. K. Shirshin, A. L. Esipovich, E. A. Kanakov, V. I. Igoshina
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Abstract

The methods of trimethylolpropane trimethacrylate synthesis by methacrylic acid esterification and methyl methacrylate transesterification with trimethylolpropane are considered. For each method, the influence of process conditions, as well as catalyst nature and concentration on the yield and quality of the target product, is described. Options for isolating trimethylolpropane trimethacrylate from reaction mixtures, as well as additional purification of the monomer, are considered.

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三甲基丙烯-三甲基丙烯酸酯合成的特点
本研究探讨了通过甲基丙烯酸酯化和甲基丙烯酸甲酯与三羟甲基丙烷发生酯交换反应合成三羟甲基丙烷三甲基丙烯酸酯的方法。对于每种方法,都介绍了工艺条件以及催化剂性质和浓度对目标产品产量和质量的影响。此外,还考虑了从反应混合物中分离三羟甲基丙烷三甲基丙烯酸酯的方案,以及单体的额外纯化。
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来源期刊
Polymer Science, Series D
Polymer Science, Series D Materials Science-Polymers and Plastics
CiteScore
0.80
自引率
0.00%
发文量
87
期刊介绍: Polymer Science, Series D  publishes useful description of engineering developments that are related to the preparation and application of glues, compounds, sealing materials, and binding agents, articles on the adhesion theory, prediction of the strength of adhesive joints, methods for the control of their properties, synthesis, and methods of structural modeling of glued joints and constructions, original articles with new scientific results, analytical reviews of the modern state in the field.
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