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IF 5.5 1区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chinese Journal of Chemistry Pub Date : 2025-03-15 DOI:10.1002/cjoc.70022
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Abstract

The rapid and efficient construction of C—C, C—N, and C—O bonds is a prominent research area in organic synthesis. A biomass derived Cu/Chitosan-800 catalyst is prepared for carbenoid insertion reactions to form C—X (X = C, N, O) bond. The substrate scope is well-demonstrated by C—H bond insertion of arenes, heteroarenes, and 1,3-diketones; N—H bond insertion of alkylamines and aromatic amines; and O—H bond insertion of carboxylic acids and diphenylphosphinic acids. Notably, the late-stage functionalization of drug molecules using this approach is also feasible. More details are discussed in the article by Tang et al. on pages 916—924.

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快速高效地构建 C-C、C-N 和 C-O 键是有机合成的一个突出研究领域。本研究制备了一种生物质衍生 Cu/Chitosan-800 催化剂,用于类碳插入反应以形成 C-X(X = C、N、O)键。该催化剂的底物范围通过以下反应得到了充分证明:炔类、杂炔类和 1,3-二酮类的 C-H 键插入反应;烷基胺和芳香胺的 N-H 键插入反应;以及羧酸和二苯基膦酸的 O-H 键插入反应。值得注意的是,使用这种方法对药物分子进行后期功能化也是可行的。更多详情请参见 Tang 等人的文章(第 916-924 页)。
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来源期刊
Chinese Journal of Chemistry
Chinese Journal of Chemistry 化学-化学综合
CiteScore
8.80
自引率
14.80%
发文量
422
审稿时长
1.7 months
期刊介绍: The Chinese Journal of Chemistry is an international forum for peer-reviewed original research results in all fields of chemistry. Founded in 1983 under the name Acta Chimica Sinica English Edition and renamed in 1990 as Chinese Journal of Chemistry, the journal publishes a stimulating mixture of Accounts, Full Papers, Notes and Communications in English.
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