Effect of Precipitation Acidity on the Structure and Morphology of α-Al2O3 Powder Particles

IF 0.7 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Inorganic Materials Pub Date : 2025-03-18 DOI:10.1134/S0020168524701590
T. S. Pozdova, D. A. Permin, M. D. Nazmutdinov, M. S. Boldin, K. A. Rubtsova, R. S. Kovylin, A. A. Moskvichev
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Abstract

The effect of the solution acidity on the phase composition and morphology of alumina powers precipitated from solution using Al(NO3)3·9H2O and NH4HCO3 was studied. In the рН range of 5–7, an amorphous precursor powder was typically formed; at рН 8–9, NH4AlCO3(OH)2 crystals were formed. When annealed, the powders precipitated from acidic solutions were 100% α-Al2O3, which was represented by agglomerated equiaxed particles sized ca. 100–200 nm. The powders prepared in neutral or alkaline solutions, when annealed, formed additional minor θ-Al2O3 and γ-Al2O3 phases in equiaxed particles sized ca. 20–25 nm.

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沉淀酸度对α-Al2O3粉末颗粒结构和形貌的影响
研究了溶液酸度对Al(NO3)3·9H2O和NH4HCO3溶液析出的氧化铝粉体相组成和形貌的影响。在рН 5-7范围内,通常形成非晶前驱体粉末;在рН 8-9处,形成了NH4AlCO3(OH)2晶体。退火后,从酸性溶液中析出的α-Al2O3粉体为100% α-Al2O3,为团聚的等轴颗粒,粒径约为100 ~ 200 nm。在中性或碱性溶液中制备的粉末在退火时,在20 ~ 25 nm的等轴颗粒中形成了次要的θ-Al2O3和γ-Al2O3相。
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来源期刊
Inorganic Materials
Inorganic Materials 工程技术-材料科学:综合
CiteScore
1.40
自引率
25.00%
发文量
80
审稿时长
3-6 weeks
期刊介绍: Inorganic Materials is a journal that publishes reviews and original articles devoted to chemistry, physics, and applications of various inorganic materials including high-purity substances and materials. The journal discusses phase equilibria, including P–T–X diagrams, and the fundamentals of inorganic materials science, which determines preparatory conditions for compounds of various compositions with specified deviations from stoichiometry. Inorganic Materials is a multidisciplinary journal covering all classes of inorganic materials. The journal welcomes manuscripts from all countries in the English or Russian language.
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