{"title":"Bis{4-(all-yloxy)-<i>N</i>'-[4-(oct-yloxy)benzyl-idene]benzohydrazidato}nickel(II).","authors":"Sultana Shakila Khan, Md Belayet Hossain Howlader, Md Chanmiya Sheikh, Ryuta Miyatake, Ennio Zangrando","doi":"10.1107/S2414314625001208","DOIUrl":null,"url":null,"abstract":"<p><p>The central Ni<sup>II</sup> atom in the title complex, [Ni(C<sub>25</sub>H<sub>31</sub>N<sub>2</sub>O<sub>3</sub>)<sub>2</sub>], is located on crystallographic inversion center and adopts a slightly distorted square-planar coordination geometry defined by the imine nitro-gen and amide oxygen donors of two chelating symmetry-related ligands in a <i>trans</i> configuration. The Ni-N and Ni-O bond lengths are 1.8685 (15) and 1.8409 (14) Å, respectively, with a chelating N-Ni-O bond angle of 83.79 (6)°. These data are in agreement with those determined for complexes of similar ligands.</p>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 Pt 2","pages":"x250120"},"PeriodicalIF":0.0000,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11904626/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1107/S2414314625001208","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/2/1 0:00:00","PubModel":"eCollection","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The central NiII atom in the title complex, [Ni(C25H31N2O3)2], is located on crystallographic inversion center and adopts a slightly distorted square-planar coordination geometry defined by the imine nitro-gen and amide oxygen donors of two chelating symmetry-related ligands in a trans configuration. The Ni-N and Ni-O bond lengths are 1.8685 (15) and 1.8409 (14) Å, respectively, with a chelating N-Ni-O bond angle of 83.79 (6)°. These data are in agreement with those determined for complexes of similar ligands.
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